X-ray and spectroscopic re-investigation of the 1: 1 complex formed between urotropine and resorcinol

S. W. Ng, Pance Naumov, A. R. Ibrahim, H. K. Fun, S. Chantrapromma, G. Wojciechowski, B. Brzezinski, J. V. Hanna

Research output: Contribution to journalArticle

Abstract

The 1:1 urotropine-resorcinol complex, which has been previously described in the non-centric C2cm space group, is redetermined in the centrosymmetric Cmcm space group. In the crystal structure, the urotropine moiety is linked to the resorcinol moiety by a single hydrogen bond [O···N = 2.769(4) Å]. The FT IR spectrum of the complex reflects the crystallographic features of the disordered structure.

Original languageEnglish (US)
Pages (from-to)89-95
Number of pages7
JournalJournal of Molecular Structure
Volume609
Issue number1-3
DOIs
StatePublished - May 30 2002

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X rays
Hydrogen bonds
Crystal structure
resorcinol

Keywords

  • C NMR
  • H NMR
  • Crystal structure
  • FT IR spectroscopy
  • Intermolecular hydrogen bond
  • Solid-state C NMR
  • Urotropine

ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

X-ray and spectroscopic re-investigation of the 1 : 1 complex formed between urotropine and resorcinol. / Ng, S. W.; Naumov, Pance; Ibrahim, A. R.; Fun, H. K.; Chantrapromma, S.; Wojciechowski, G.; Brzezinski, B.; Hanna, J. V.

In: Journal of Molecular Structure, Vol. 609, No. 1-3, 30.05.2002, p. 89-95.

Research output: Contribution to journalArticle

Ng, SW, Naumov, P, Ibrahim, AR, Fun, HK, Chantrapromma, S, Wojciechowski, G, Brzezinski, B & Hanna, JV 2002, 'X-ray and spectroscopic re-investigation of the 1: 1 complex formed between urotropine and resorcinol', Journal of Molecular Structure, vol. 609, no. 1-3, pp. 89-95. https://doi.org/10.1016/S0022-2860(01)00945-0
Ng, S. W. ; Naumov, Pance ; Ibrahim, A. R. ; Fun, H. K. ; Chantrapromma, S. ; Wojciechowski, G. ; Brzezinski, B. ; Hanna, J. V. / X-ray and spectroscopic re-investigation of the 1 : 1 complex formed between urotropine and resorcinol. In: Journal of Molecular Structure. 2002 ; Vol. 609, No. 1-3. pp. 89-95.
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abstract = "The 1:1 urotropine-resorcinol complex, which has been previously described in the non-centric C2cm space group, is redetermined in the centrosymmetric Cmcm space group. In the crystal structure, the urotropine moiety is linked to the resorcinol moiety by a single hydrogen bond [O···N = 2.769(4) {\AA}]. The FT IR spectrum of the complex reflects the crystallographic features of the disordered structure.",
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