Joint spectroscopic (ESR, electronic absorption and FT IR) and voltammetric (square-wave and cyclic voltammetry) techniques were employed to investigate the properties of copper adducts with cysteine, N-acetylcysteine and methionine under aerobic and anaerobic conditions. The metal oxidation state in the solid and solvated adducts adheres to the presence of oxygen, whereas ESR results (g∥ = 2.245, g⊥ = 2.059, A∥ = 170 Gauss) reveal tetragonally distorted octahedral copper(II) environment under aerobic circumstances. In presence of the thiol and thioether ligands under nitrogen voltammetric measurements evidence formation of copper(I) species.
|Original language||English (US)|
|Number of pages||7|
|Journal||Polish Journal of Chemistry|
|State||Published - May 1 2002|
- Copper complexes
- Redox reactions
ASJC Scopus subject areas