Vibrational studies of the solid imidazole and pyridine adducts of metal(II) saccharinates. Part II. Mn(II) and Fe(II) imidazole saccharinates

Pance Naumov, G. Jovanovski, A. Todorovska

    Research output: Contribution to journalArticle

    Abstract

    Novel adducts of Mn(II) and Fe(II) saccharinates with imidazole were synthesized and their protonated and deuterated analogues were investigated by the means of FT-IR spectroscopy at room and at liquid-nitrogen boiling temperature. The appearance of the characteristic OH/OD, NH, CO and SO2 stretching bands was employed together with the earlier spectra-structure correlations to predict certain structural details about the complexes. The IR spectra reveal pronounced structural similarity and possible isomorphism with the Co and Ni adducts of formula [M(C3H4N2)4(H2O) 2](C7H4NO3S)2. There is a single crystallographic type of asymmetrically bonded water molecules in the structure. All saccharinato ions are structurally equal. The O-S-O angles should be similar with those in Mg(sac)2·7H2O and Na3(sac)3·2H2O.

    Original languageEnglish (US)
    Pages (from-to)341-345
    Number of pages5
    JournalJournal of Molecular Structure
    Volume563
    Issue number564
    DOIs
    StatePublished - May 28 2001

    Fingerprint

    Liquid nitrogen
    Carbon Monoxide
    Boiling liquids
    Stretching
    Infrared spectroscopy
    Metals
    Ions
    Molecules
    Water
    Temperature
    pyridine
    imidazole

    Keywords

    • Deuteration
    • FT-IR
    • Imidazole adduct
    • Saccharinate
    • Spectra-structure correlations

    ASJC Scopus subject areas

    • Analytical Chemistry
    • Spectroscopy
    • Organic Chemistry
    • Inorganic Chemistry

    Cite this

    Vibrational studies of the solid imidazole and pyridine adducts of metal(II) saccharinates. Part II. Mn(II) and Fe(II) imidazole saccharinates. / Naumov, Pance; Jovanovski, G.; Todorovska, A.

    In: Journal of Molecular Structure, Vol. 563, No. 564, 28.05.2001, p. 341-345.

    Research output: Contribution to journalArticle

    @article{820ec4b7dc594a029de2d82b8a8f72d2,
    title = "Vibrational studies of the solid imidazole and pyridine adducts of metal(II) saccharinates. Part II. Mn(II) and Fe(II) imidazole saccharinates",
    abstract = "Novel adducts of Mn(II) and Fe(II) saccharinates with imidazole were synthesized and their protonated and deuterated analogues were investigated by the means of FT-IR spectroscopy at room and at liquid-nitrogen boiling temperature. The appearance of the characteristic OH/OD, NH, CO and SO2 stretching bands was employed together with the earlier spectra-structure correlations to predict certain structural details about the complexes. The IR spectra reveal pronounced structural similarity and possible isomorphism with the Co and Ni adducts of formula [M(C3H4N2)4(H2O) 2](C7H4NO3S)2. There is a single crystallographic type of asymmetrically bonded water molecules in the structure. All saccharinato ions are structurally equal. The O-S-O angles should be similar with those in Mg(sac)2·7H2O and Na3(sac)3·2H2O.",
    keywords = "Deuteration, FT-IR, Imidazole adduct, Saccharinate, Spectra-structure correlations",
    author = "Pance Naumov and G. Jovanovski and A. Todorovska",
    year = "2001",
    month = "5",
    day = "28",
    doi = "10.1016/S0022-2860(00)00937-6",
    language = "English (US)",
    volume = "563",
    pages = "341--345",
    journal = "Journal of Molecular Structure",
    issn = "0022-2860",
    publisher = "Elsevier",
    number = "564",

    }

    TY - JOUR

    T1 - Vibrational studies of the solid imidazole and pyridine adducts of metal(II) saccharinates. Part II. Mn(II) and Fe(II) imidazole saccharinates

    AU - Naumov, Pance

    AU - Jovanovski, G.

    AU - Todorovska, A.

    PY - 2001/5/28

    Y1 - 2001/5/28

    N2 - Novel adducts of Mn(II) and Fe(II) saccharinates with imidazole were synthesized and their protonated and deuterated analogues were investigated by the means of FT-IR spectroscopy at room and at liquid-nitrogen boiling temperature. The appearance of the characteristic OH/OD, NH, CO and SO2 stretching bands was employed together with the earlier spectra-structure correlations to predict certain structural details about the complexes. The IR spectra reveal pronounced structural similarity and possible isomorphism with the Co and Ni adducts of formula [M(C3H4N2)4(H2O) 2](C7H4NO3S)2. There is a single crystallographic type of asymmetrically bonded water molecules in the structure. All saccharinato ions are structurally equal. The O-S-O angles should be similar with those in Mg(sac)2·7H2O and Na3(sac)3·2H2O.

    AB - Novel adducts of Mn(II) and Fe(II) saccharinates with imidazole were synthesized and their protonated and deuterated analogues were investigated by the means of FT-IR spectroscopy at room and at liquid-nitrogen boiling temperature. The appearance of the characteristic OH/OD, NH, CO and SO2 stretching bands was employed together with the earlier spectra-structure correlations to predict certain structural details about the complexes. The IR spectra reveal pronounced structural similarity and possible isomorphism with the Co and Ni adducts of formula [M(C3H4N2)4(H2O) 2](C7H4NO3S)2. There is a single crystallographic type of asymmetrically bonded water molecules in the structure. All saccharinato ions are structurally equal. The O-S-O angles should be similar with those in Mg(sac)2·7H2O and Na3(sac)3·2H2O.

    KW - Deuteration

    KW - FT-IR

    KW - Imidazole adduct

    KW - Saccharinate

    KW - Spectra-structure correlations

    UR - http://www.scopus.com/inward/record.url?scp=0035962548&partnerID=8YFLogxK

    UR - http://www.scopus.com/inward/citedby.url?scp=0035962548&partnerID=8YFLogxK

    U2 - 10.1016/S0022-2860(00)00937-6

    DO - 10.1016/S0022-2860(00)00937-6

    M3 - Article

    VL - 563

    SP - 341

    EP - 345

    JO - Journal of Molecular Structure

    JF - Journal of Molecular Structure

    SN - 0022-2860

    IS - 564

    ER -