Underwater Organic Solar Cells via Selective Removal of Electron Acceptors near the Top Electrode

Jaemin Kong, Dennis Nordlund, Jong Sung Jin, Sang Yup Kim, Sun Mi Jin, Di Huang, Yifan Zheng, Christopher Karpovich, Genevieve Sertic, Hanyu Wang, Jinyang Li, Guoming Weng, Francisco Antonio, Marina Mariano, Stephen Maclean, Tenghooi Goh, Jin Young Kim, André D. Taylor

Research output: Contribution to journalArticle

Abstract

Electron acceptor degradation of organic solar cells is considered a main contributor to performance instability and a barrier for the commercialization of organic solar cells. Here, we selectively remove the electron acceptors on the surface of donor:acceptor blend films using a tape stripping technique. The near-edge X-ray absorption fine structure (NEXAFS) spectrum reveals that only 6% of the acceptor component is left on the blend film surface after the tape stripping, creating a polymer-rich surface. The optimized morphology avoids direct contact of electron acceptors with the oxygen and water molecules from the film surface. Moreover, the polymer-rich surface dramatically enhances the adhesion between the photoactive layer and the top metal electrode, which prevents delamination of the electrode. Our results finally demonstrate that the selective removal of electron acceptors near the top electrode facilitates the realization of highly durable organic solar cells that can even function under water without encapsulation.

Original languageEnglish (US)
Pages (from-to)1034-1041
Number of pages8
JournalACS Energy Letters
Volume4
Issue number5
DOIs
StatePublished - May 10 2019

ASJC Scopus subject areas

  • Chemistry (miscellaneous)
  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Materials Chemistry

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  • Cite this

    Kong, J., Nordlund, D., Jin, J. S., Kim, S. Y., Jin, S. M., Huang, D., Zheng, Y., Karpovich, C., Sertic, G., Wang, H., Li, J., Weng, G., Antonio, F., Mariano, M., Maclean, S., Goh, T., Kim, J. Y., & Taylor, A. D. (2019). Underwater Organic Solar Cells via Selective Removal of Electron Acceptors near the Top Electrode. ACS Energy Letters, 4(5), 1034-1041. https://doi.org/10.1021/acsenergylett.9b00274