Thin films of block copolymer-homopolymer blends with a continuously tunable density of spherical microdomains

John M. Papalia, Andrew P. Marencic, Douglas H. Adamson, Paul M. Chaikin, Richard A. Register

    Research output: Contribution to journalArticle

    Abstract

    A study was conducted to demonstrate the advantage of the through-film structures of block copolymer thin films and the behavior of block copolymer and homopolymer blends in continuously tuning the areal density of micelles from zero up to values comparable to that for a monolayer of neat block copolymer. This was accomplished by control of the film thickness at a constant ratio of block copolymer to homopolymer. The approach relied on the fact that the two dissimilar blocks in the copolymer had preferential interactions with the substrate and with the free surface, leading to complete wetting of each surface by one of the blocks. The approach required that the minority component wetted at least one of the two surfaces. It was demonstrated that the direct connection between micelle areal density and film thickness was a consequence of the fact that the material's composition was uniform on length scales larger than the individual micelle.

    Original languageEnglish (US)
    Pages (from-to)6946-6949
    Number of pages4
    JournalMacromolecules
    Volume43
    Issue number17
    DOIs
    StatePublished - Sep 14 2010

    Fingerprint

    Homopolymerization
    Block copolymers
    Micelles
    Thin films
    Film thickness
    Wetting
    Monolayers
    Copolymers
    Tuning
    Substrates
    Chemical analysis

    ASJC Scopus subject areas

    • Organic Chemistry
    • Materials Chemistry
    • Polymers and Plastics
    • Inorganic Chemistry

    Cite this

    Papalia, J. M., Marencic, A. P., Adamson, D. H., Chaikin, P. M., & Register, R. A. (2010). Thin films of block copolymer-homopolymer blends with a continuously tunable density of spherical microdomains. Macromolecules, 43(17), 6946-6949. https://doi.org/10.1021/ma101458m

    Thin films of block copolymer-homopolymer blends with a continuously tunable density of spherical microdomains. / Papalia, John M.; Marencic, Andrew P.; Adamson, Douglas H.; Chaikin, Paul M.; Register, Richard A.

    In: Macromolecules, Vol. 43, No. 17, 14.09.2010, p. 6946-6949.

    Research output: Contribution to journalArticle

    Papalia, JM, Marencic, AP, Adamson, DH, Chaikin, PM & Register, RA 2010, 'Thin films of block copolymer-homopolymer blends with a continuously tunable density of spherical microdomains', Macromolecules, vol. 43, no. 17, pp. 6946-6949. https://doi.org/10.1021/ma101458m
    Papalia, John M. ; Marencic, Andrew P. ; Adamson, Douglas H. ; Chaikin, Paul M. ; Register, Richard A. / Thin films of block copolymer-homopolymer blends with a continuously tunable density of spherical microdomains. In: Macromolecules. 2010 ; Vol. 43, No. 17. pp. 6946-6949.
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