Thermodynamically stable pickering emulsions

Stefano Sacanna, W. K. Kegel, A. P. Philipse

Research output: Contribution to journalArticle

Abstract

We show that under appropriate conditions, mixtures of oil, water, and nanoparticles form thermodynamically stable oil-in-water emulsions with monodisperse droplet diameters in the range of 30-150 nm. This observation challenges current wisdom that so-called Pickering emulsions are at most metastable and points to a new class of mesoscopic equilibrium structures. Thermodynamic stability is demonstrated by the spontaneous evolution of binary droplet mixtures towards one intermediate size distribution. Equilibrium interfacial curvature due to an asymmetric charge distribution induced by adsorbed colloids explains the growth of emulsion droplets upon salt addition. Moreover, the existence of a minimal radius of curvature with a concomitant expulsion of excess oil is in close analogy with microemulsions.

Original languageEnglish (US)
Article number158301
JournalPhysical Review Letters
Volume98
Issue number15
DOIs
StatePublished - Apr 12 2007

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emulsions
oils
curvature
expulsion
charge distribution
water
binary mixtures
colloids
salts
nanoparticles
thermodynamics
radii

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

Thermodynamically stable pickering emulsions. / Sacanna, Stefano; Kegel, W. K.; Philipse, A. P.

In: Physical Review Letters, Vol. 98, No. 15, 158301, 12.04.2007.

Research output: Contribution to journalArticle

Sacanna, Stefano ; Kegel, W. K. ; Philipse, A. P. / Thermodynamically stable pickering emulsions. In: Physical Review Letters. 2007 ; Vol. 98, No. 15.
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