Thermal behaviour of the N-donor adducts of metal saccharinates II. 1,10-phenanthroline saccharinato complexes of Co(II), Ni(II), Cu(II), Zn(II) and Pb(II)

Pance Naumov, O. Grupče, V. Jordanovska, B. Boyanov, G. Jovanovski

    Research output: Contribution to journalArticle

    Abstract

    Adducts of Co(II), Ni(II), Cu(II), Zn(II) and Pb(II) saccharinates with 1,10-phenathroline were synthesized and their thermoanalytical (TG, DTG and DTA) curves in the 20-1000°C temperature interval and static air atmosphere were recorded. The complexes are best represented as M(C12H8N2)x(C7 H4NO3S)2·yH2O (x=2, 2, 2, 2 and 1;y= 1, 1, 2, 1 and 2 for M=Co, Ni, Cu, Zn and Pb, respectively). The decomposition of the compounds regularly started with dehydration, followed by loss of the phenanthroline ligand(s). The structures of the Cu and Pb complexes are notably different from other compounds. FTIR spectra of the title compounds in the region of the OH, CO and SO2 stretching vibrations were also studied. The pronounced similarity of the spectra of Co, Ni and Zn adducts indicates possible isomorphism among them.

    Original languageEnglish (US)
    Pages (from-to)871-880
    Number of pages10
    JournalJournal of Thermal Analysis and Calorimetry
    Volume65
    Issue number3
    DOIs
    StatePublished - Oct 16 2001

    Fingerprint

    Phenanthrolines
    Carbon Monoxide
    Dehydration
    Differential thermal analysis
    adducts
    Stretching
    Metals
    Ligands
    Decomposition
    isomorphism
    Air
    dehydration
    metals
    thermal analysis
    intervals
    decomposition
    atmospheres
    vibration
    Temperature
    ligands

    Keywords

    • 1,10-phenanthroline
    • N-donor adducts
    • Saccharinates
    • Thermal decomposition

    ASJC Scopus subject areas

    • Condensed Matter Physics
    • Physical and Theoretical Chemistry

    Cite this

    Thermal behaviour of the N-donor adducts of metal saccharinates II. 1,10-phenanthroline saccharinato complexes of Co(II), Ni(II), Cu(II), Zn(II) and Pb(II). / Naumov, Pance; Grupče, O.; Jordanovska, V.; Boyanov, B.; Jovanovski, G.

    In: Journal of Thermal Analysis and Calorimetry, Vol. 65, No. 3, 16.10.2001, p. 871-880.

    Research output: Contribution to journalArticle

    @article{52a16a8075384865865d080c87ccf35b,
    title = "Thermal behaviour of the N-donor adducts of metal saccharinates II. 1,10-phenanthroline saccharinato complexes of Co(II), Ni(II), Cu(II), Zn(II) and Pb(II)",
    abstract = "Adducts of Co(II), Ni(II), Cu(II), Zn(II) and Pb(II) saccharinates with 1,10-phenathroline were synthesized and their thermoanalytical (TG, DTG and DTA) curves in the 20-1000°C temperature interval and static air atmosphere were recorded. The complexes are best represented as M(C12H8N2)x(C7 H4NO3S)2·yH2O (x=2, 2, 2, 2 and 1;y= 1, 1, 2, 1 and 2 for M=Co, Ni, Cu, Zn and Pb, respectively). The decomposition of the compounds regularly started with dehydration, followed by loss of the phenanthroline ligand(s). The structures of the Cu and Pb complexes are notably different from other compounds. FTIR spectra of the title compounds in the region of the OH, CO and SO2 stretching vibrations were also studied. The pronounced similarity of the spectra of Co, Ni and Zn adducts indicates possible isomorphism among them.",
    keywords = "1,10-phenanthroline, N-donor adducts, Saccharinates, Thermal decomposition",
    author = "Pance Naumov and O. Grupče and V. Jordanovska and B. Boyanov and G. Jovanovski",
    year = "2001",
    month = "10",
    day = "16",
    doi = "10.1023/A:1011992519154",
    language = "English (US)",
    volume = "65",
    pages = "871--880",
    journal = "Journal of Thermal Analysis and Calorimetry",
    issn = "1388-6150",
    publisher = "Springer Netherlands",
    number = "3",

    }

    TY - JOUR

    T1 - Thermal behaviour of the N-donor adducts of metal saccharinates II. 1,10-phenanthroline saccharinato complexes of Co(II), Ni(II), Cu(II), Zn(II) and Pb(II)

    AU - Naumov, Pance

    AU - Grupče, O.

    AU - Jordanovska, V.

    AU - Boyanov, B.

    AU - Jovanovski, G.

    PY - 2001/10/16

    Y1 - 2001/10/16

    N2 - Adducts of Co(II), Ni(II), Cu(II), Zn(II) and Pb(II) saccharinates with 1,10-phenathroline were synthesized and their thermoanalytical (TG, DTG and DTA) curves in the 20-1000°C temperature interval and static air atmosphere were recorded. The complexes are best represented as M(C12H8N2)x(C7 H4NO3S)2·yH2O (x=2, 2, 2, 2 and 1;y= 1, 1, 2, 1 and 2 for M=Co, Ni, Cu, Zn and Pb, respectively). The decomposition of the compounds regularly started with dehydration, followed by loss of the phenanthroline ligand(s). The structures of the Cu and Pb complexes are notably different from other compounds. FTIR spectra of the title compounds in the region of the OH, CO and SO2 stretching vibrations were also studied. The pronounced similarity of the spectra of Co, Ni and Zn adducts indicates possible isomorphism among them.

    AB - Adducts of Co(II), Ni(II), Cu(II), Zn(II) and Pb(II) saccharinates with 1,10-phenathroline were synthesized and their thermoanalytical (TG, DTG and DTA) curves in the 20-1000°C temperature interval and static air atmosphere were recorded. The complexes are best represented as M(C12H8N2)x(C7 H4NO3S)2·yH2O (x=2, 2, 2, 2 and 1;y= 1, 1, 2, 1 and 2 for M=Co, Ni, Cu, Zn and Pb, respectively). The decomposition of the compounds regularly started with dehydration, followed by loss of the phenanthroline ligand(s). The structures of the Cu and Pb complexes are notably different from other compounds. FTIR spectra of the title compounds in the region of the OH, CO and SO2 stretching vibrations were also studied. The pronounced similarity of the spectra of Co, Ni and Zn adducts indicates possible isomorphism among them.

    KW - 1,10-phenanthroline

    KW - N-donor adducts

    KW - Saccharinates

    KW - Thermal decomposition

    UR - http://www.scopus.com/inward/record.url?scp=0034816887&partnerID=8YFLogxK

    UR - http://www.scopus.com/inward/citedby.url?scp=0034816887&partnerID=8YFLogxK

    U2 - 10.1023/A:1011992519154

    DO - 10.1023/A:1011992519154

    M3 - Article

    VL - 65

    SP - 871

    EP - 880

    JO - Journal of Thermal Analysis and Calorimetry

    JF - Journal of Thermal Analysis and Calorimetry

    SN - 1388-6150

    IS - 3

    ER -