Theoretical investigations of l = 5/2 quadrupolar spin dynamics in the sudden-passage regime

Jamie D. Walls, Kwang Hun Lim, John W. Logan, Jeffry T. Urban, Alexej Jerschow, Alexander Pines

Research output: Contribution to journalArticle

Abstract

The theoretical investigations of quadrupolar spin dynmaics was studied using bimodal Floquet theory. Effective transfer between five-quantum and triple-quantum coherences was observed in between rotary resonance conditions. The results revealed that rotary resonance effects occur when the strength of the radio-frequency irradiation matches the sample spinning speed.

Original languageEnglish (US)
Pages (from-to)518-532
Number of pages15
JournalJournal of Chemical Physics
Volume117
Issue number2
DOIs
StatePublished - Jul 8 2002

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Spin dynamics
spin dynamics
metal spinning
radio frequencies
Irradiation
irradiation

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Theoretical investigations of l = 5/2 quadrupolar spin dynamics in the sudden-passage regime. / Walls, Jamie D.; Lim, Kwang Hun; Logan, John W.; Urban, Jeffry T.; Jerschow, Alexej; Pines, Alexander.

In: Journal of Chemical Physics, Vol. 117, No. 2, 08.07.2002, p. 518-532.

Research output: Contribution to journalArticle

Walls, Jamie D. ; Lim, Kwang Hun ; Logan, John W. ; Urban, Jeffry T. ; Jerschow, Alexej ; Pines, Alexander. / Theoretical investigations of l = 5/2 quadrupolar spin dynamics in the sudden-passage regime. In: Journal of Chemical Physics. 2002 ; Vol. 117, No. 2. pp. 518-532.
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