The NEUF-DIX space project - Non-EquilibriUm Fluctuations during DIffusion in compleX liquids

Philipp Baaske, Henri Bataller, Marco Braibanti, Marina Carpineti, Roberto Cerbino, Fabrizio Croccolo, Aleksandar Donev, Werner Köhler, José M. Ortiz de Zárate, Alberto Vailati

Research output: Contribution to journalArticle

Abstract

Abstract.: Diffusion and thermal diffusion processes in a liquid mixture are accompanied by long-range non-equilibrium fluctuations, whose amplitude is orders of magnitude larger than that of equilibrium fluctuations. The mean-square amplitude of the non-equilibrium fluctuations presents a scale-free power law behavior q-4 as a function of the wave vector q, but the divergence of the amplitude of the fluctuations at small wave vectors is prevented by the presence of gravity. In microgravity conditions the non-equilibrium fluctuations are fully developed and span all the available length scales up to the macroscopic size of the systems in the direction parallel to the applied gradient. Available theoretical models are based on linearized hydrodynamics and provide an adequate description of the statics and dynamics of the fluctuations in the presence of small temperature/concentration gradients and under stationary or quasi-stationary conditions. We describe a project aimed at the investigation of Non-EquilibriUm Fluctuations during DIffusion in compleX liquids (NEUF-DIX). The focus of the project is on the investigation in micro-gravity conditions of the non-equilibrium fluctuations in complex liquids, trying to tackle several challenging problems that emerged during the latest years, such as the theoretical predictions of Casimir-like forces induced by non-equilibrium fluctuations; the understanding of the non-equilibrium fluctuations in multi-component mixtures including a polymer, both in relation to the transport coefficients and to their behavior close to a glass transition; the understanding of the non-equilibrium fluctuations in concentrated colloidal suspensions, a problem closely related with the detection of Casimir forces; and the investigation of the development of fluctuations during transient diffusion. We envision to parallel these experiments with state-of-the-art multi-scale simulations. Graphical abstract: [Figure not available: see fulltext.]

Original languageEnglish (US)
Article number119
JournalEuropean Physical Journal E
Volume39
Issue number12
DOIs
StatePublished - Dec 1 2016

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Microgravity
Gravitation
Liquids
Thermal Diffusion
liquids
Weightlessness
Thermal diffusion
Hydrodynamics
Glass
Glass transition
Suspensions
Polymers
Theoretical Models
Temperature
microgravity
Experiments
gradients
thermal diffusion
colloids
divergence

Keywords

  • Topical Issue: Non-isothermal transport in complex fluids

ASJC Scopus subject areas

  • Biotechnology
  • Biophysics
  • Chemistry(all)
  • Materials Science(all)
  • Surfaces and Interfaces

Cite this

Baaske, P., Bataller, H., Braibanti, M., Carpineti, M., Cerbino, R., Croccolo, F., ... Vailati, A. (2016). The NEUF-DIX space project - Non-EquilibriUm Fluctuations during DIffusion in compleX liquids. European Physical Journal E, 39(12), [119]. https://doi.org/10.1140/epje/i2016-16119-1

The NEUF-DIX space project - Non-EquilibriUm Fluctuations during DIffusion in compleX liquids. / Baaske, Philipp; Bataller, Henri; Braibanti, Marco; Carpineti, Marina; Cerbino, Roberto; Croccolo, Fabrizio; Donev, Aleksandar; Köhler, Werner; Ortiz de Zárate, José M.; Vailati, Alberto.

In: European Physical Journal E, Vol. 39, No. 12, 119, 01.12.2016.

Research output: Contribution to journalArticle

Baaske, P, Bataller, H, Braibanti, M, Carpineti, M, Cerbino, R, Croccolo, F, Donev, A, Köhler, W, Ortiz de Zárate, JM & Vailati, A 2016, 'The NEUF-DIX space project - Non-EquilibriUm Fluctuations during DIffusion in compleX liquids', European Physical Journal E, vol. 39, no. 12, 119. https://doi.org/10.1140/epje/i2016-16119-1
Baaske, Philipp ; Bataller, Henri ; Braibanti, Marco ; Carpineti, Marina ; Cerbino, Roberto ; Croccolo, Fabrizio ; Donev, Aleksandar ; Köhler, Werner ; Ortiz de Zárate, José M. ; Vailati, Alberto. / The NEUF-DIX space project - Non-EquilibriUm Fluctuations during DIffusion in compleX liquids. In: European Physical Journal E. 2016 ; Vol. 39, No. 12.
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AB - Abstract.: Diffusion and thermal diffusion processes in a liquid mixture are accompanied by long-range non-equilibrium fluctuations, whose amplitude is orders of magnitude larger than that of equilibrium fluctuations. The mean-square amplitude of the non-equilibrium fluctuations presents a scale-free power law behavior q-4 as a function of the wave vector q, but the divergence of the amplitude of the fluctuations at small wave vectors is prevented by the presence of gravity. In microgravity conditions the non-equilibrium fluctuations are fully developed and span all the available length scales up to the macroscopic size of the systems in the direction parallel to the applied gradient. Available theoretical models are based on linearized hydrodynamics and provide an adequate description of the statics and dynamics of the fluctuations in the presence of small temperature/concentration gradients and under stationary or quasi-stationary conditions. We describe a project aimed at the investigation of Non-EquilibriUm Fluctuations during DIffusion in compleX liquids (NEUF-DIX). The focus of the project is on the investigation in micro-gravity conditions of the non-equilibrium fluctuations in complex liquids, trying to tackle several challenging problems that emerged during the latest years, such as the theoretical predictions of Casimir-like forces induced by non-equilibrium fluctuations; the understanding of the non-equilibrium fluctuations in multi-component mixtures including a polymer, both in relation to the transport coefficients and to their behavior close to a glass transition; the understanding of the non-equilibrium fluctuations in concentrated colloidal suspensions, a problem closely related with the detection of Casimir forces; and the investigation of the development of fluctuations during transient diffusion. We envision to parallel these experiments with state-of-the-art multi-scale simulations. Graphical abstract: [Figure not available: see fulltext.]

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