The crystal structure of the Dess-Martin periodinane

Albert Schröckeneder, Desiree Stichnoth, Peter Mayer, Dirk Trauner

Research output: Contribution to journalArticle

Abstract

We report the elusive X-ray structure of the Dess-Martin periodinane (DMP), a hypervalent iodine reagent popular amongst synthetic chemists. In the solid state, the highly crystalline compound forms an intricate coordination polymer held together by intermolecular halogen and hydrogen bonds.

Original languageEnglish (US)
Pages (from-to)1523-1527
Number of pages5
JournalBeilstein Journal of Organic Chemistry
Volume8
DOIs
StatePublished - Sep 12 2012

Fingerprint

Halogens
Iodine
Hydrogen bonds
Polymers
Crystal structure
Crystalline materials
X rays
1,1,1-triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one

Keywords

  • Crystal structure
  • Dess-Martin periodinane
  • Halogen bonds
  • Hypervalent iodine
  • Oxidant

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Schröckeneder, A., Stichnoth, D., Mayer, P., & Trauner, D. (2012). The crystal structure of the Dess-Martin periodinane. Beilstein Journal of Organic Chemistry, 8, 1523-1527. https://doi.org/10.3762/bjoc.8.172

The crystal structure of the Dess-Martin periodinane. / Schröckeneder, Albert; Stichnoth, Desiree; Mayer, Peter; Trauner, Dirk.

In: Beilstein Journal of Organic Chemistry, Vol. 8, 12.09.2012, p. 1523-1527.

Research output: Contribution to journalArticle

Schröckeneder, A, Stichnoth, D, Mayer, P & Trauner, D 2012, 'The crystal structure of the Dess-Martin periodinane', Beilstein Journal of Organic Chemistry, vol. 8, pp. 1523-1527. https://doi.org/10.3762/bjoc.8.172
Schröckeneder, Albert ; Stichnoth, Desiree ; Mayer, Peter ; Trauner, Dirk. / The crystal structure of the Dess-Martin periodinane. In: Beilstein Journal of Organic Chemistry. 2012 ; Vol. 8. pp. 1523-1527.
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