The crystal structure of copper(II) malonate trihydrate

Pance Naumov, Mirjana Ristova, Bojan Šoptrajanov, Michael G.B. Drew, Seik Weng Ng

Research output: Contribution to journalArticle

Abstract

The compound having an empirical formula Cu8C24H64O56, corresponding to copper(II) malonate trihydrate, is in fact the 2 : 1 co-crystal bis(diaquadimalonatocopper-tetraaquacopper)-[(diaquadimalonatocopper)- bis(tetraaquacopper)](2+) diaquadimalonatocuprate(2-), [(H2O)2Cu(O2CCH2CO2) 2 · Cu(H2O)4]2 · [(H2O)2Cu(O2CCH2CO2) 2 · {Cu-(H2O)4}2]2+ [(H2O)2Cu(O2CCH2CO2) 2]2-. The compound crystallizes in the monoclinic P21/c space group, with a = 14.96(2), b = 14.97(2), c = 26.00(3) Å; β = 103.91(1)°; Z = 4, ρcalc = 2.064 g cm-3.

Original languageEnglish (US)
Pages (from-to)701-711
Number of pages11
JournalCroatica Chemica Acta
Volume75
Issue number3
StatePublished - Aug 1 2002

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Copper
Crystal structure
Crystals
malonic acid

Keywords

  • Coordination
  • Copper
  • Crystal structure
  • Hydrogen bonding
  • Malonate

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Naumov, P., Ristova, M., Šoptrajanov, B., Drew, M. G. B., & Ng, S. W. (2002). The crystal structure of copper(II) malonate trihydrate. Croatica Chemica Acta, 75(3), 701-711.

The crystal structure of copper(II) malonate trihydrate. / Naumov, Pance; Ristova, Mirjana; Šoptrajanov, Bojan; Drew, Michael G.B.; Ng, Seik Weng.

In: Croatica Chemica Acta, Vol. 75, No. 3, 01.08.2002, p. 701-711.

Research output: Contribution to journalArticle

Naumov, P, Ristova, M, Šoptrajanov, B, Drew, MGB & Ng, SW 2002, 'The crystal structure of copper(II) malonate trihydrate', Croatica Chemica Acta, vol. 75, no. 3, pp. 701-711.
Naumov P, Ristova M, Šoptrajanov B, Drew MGB, Ng SW. The crystal structure of copper(II) malonate trihydrate. Croatica Chemica Acta. 2002 Aug 1;75(3):701-711.
Naumov, Pance ; Ristova, Mirjana ; Šoptrajanov, Bojan ; Drew, Michael G.B. ; Ng, Seik Weng. / The crystal structure of copper(II) malonate trihydrate. In: Croatica Chemica Acta. 2002 ; Vol. 75, No. 3. pp. 701-711.
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AU - Naumov, Pance

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AU - Šoptrajanov, Bojan

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AU - Ng, Seik Weng

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N2 - The compound having an empirical formula Cu8C24H64O56, corresponding to copper(II) malonate trihydrate, is in fact the 2 : 1 co-crystal bis(diaquadimalonatocopper-tetraaquacopper)-[(diaquadimalonatocopper)- bis(tetraaquacopper)](2+) diaquadimalonatocuprate(2-), [(H2O)2Cu(O2CCH2CO2) 2 · Cu(H2O)4]2 · [(H2O)2Cu(O2CCH2CO2) 2 · {Cu-(H2O)4}2]2+ [(H2O)2Cu(O2CCH2CO2) 2]2-. The compound crystallizes in the monoclinic P21/c space group, with a = 14.96(2), b = 14.97(2), c = 26.00(3) Å; β = 103.91(1)°; Z = 4, ρcalc = 2.064 g cm-3.

AB - The compound having an empirical formula Cu8C24H64O56, corresponding to copper(II) malonate trihydrate, is in fact the 2 : 1 co-crystal bis(diaquadimalonatocopper-tetraaquacopper)-[(diaquadimalonatocopper)- bis(tetraaquacopper)](2+) diaquadimalonatocuprate(2-), [(H2O)2Cu(O2CCH2CO2) 2 · Cu(H2O)4]2 · [(H2O)2Cu(O2CCH2CO2) 2 · {Cu-(H2O)4}2]2+ [(H2O)2Cu(O2CCH2CO2) 2]2-. The compound crystallizes in the monoclinic P21/c space group, with a = 14.96(2), b = 14.97(2), c = 26.00(3) Å; β = 103.91(1)°; Z = 4, ρcalc = 2.064 g cm-3.

KW - Coordination

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