Synthesis and spectroscopic studies of the nicotinamide adducts of Cobalt(II), Nickel(II) and Zinc(II) chlorides

S. Çakir, E. Biçer, H. Içbudak, Pance Naumov, H. Korkmaz, O. Çakir

    Research output: Contribution to journalArticle

    Abstract

    Nicotinamide (na) adducts of Co(II), Ni(II) and Zn(II) chlorides are synthesized and characterized by thermoanalytical methods (TG, DTG, DTA), FT IR (4000-400 cm-1) and UV/Vis spectroscopy. Structural similarity is inferred between the octahedral Co and Ni compounds of type [M(na)2(H2O)4]Cl2. The tetrahedral Zn complex [Zn(na)2Cl2] presents a different structure. The coordination of the metal ions in the Co and Ni adducts modelled by semiempirical theoretical methods compares well with the structural data for [Ni(na)2(H2O)4](NO)2·2H2 O.

    Original languageEnglish (US)
    Pages (from-to)371-377
    Number of pages7
    JournalPolish Journal of Chemistry
    Volume75
    Issue number3
    StatePublished - Dec 1 2001

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    Zinc chloride
    Niacinamide
    Cobalt
    Nickel
    Ultraviolet spectroscopy
    Differential thermal analysis
    Metal ions
    Chlorides

    Keywords

    • FT IR
    • Nicotinamide adducts
    • Semiempirical calculations
    • Synthesis
    • UV/Vis spectra

    ASJC Scopus subject areas

    • Chemistry(all)

    Cite this

    Çakir, S., Biçer, E., Içbudak, H., Naumov, P., Korkmaz, H., & Çakir, O. (2001). Synthesis and spectroscopic studies of the nicotinamide adducts of Cobalt(II), Nickel(II) and Zinc(II) chlorides. Polish Journal of Chemistry, 75(3), 371-377.

    Synthesis and spectroscopic studies of the nicotinamide adducts of Cobalt(II), Nickel(II) and Zinc(II) chlorides. / Çakir, S.; Biçer, E.; Içbudak, H.; Naumov, Pance; Korkmaz, H.; Çakir, O.

    In: Polish Journal of Chemistry, Vol. 75, No. 3, 01.12.2001, p. 371-377.

    Research output: Contribution to journalArticle

    Çakir, S, Biçer, E, Içbudak, H, Naumov, P, Korkmaz, H & Çakir, O 2001, 'Synthesis and spectroscopic studies of the nicotinamide adducts of Cobalt(II), Nickel(II) and Zinc(II) chlorides', Polish Journal of Chemistry, vol. 75, no. 3, pp. 371-377.
    Çakir, S. ; Biçer, E. ; Içbudak, H. ; Naumov, Pance ; Korkmaz, H. ; Çakir, O. / Synthesis and spectroscopic studies of the nicotinamide adducts of Cobalt(II), Nickel(II) and Zinc(II) chlorides. In: Polish Journal of Chemistry. 2001 ; Vol. 75, No. 3. pp. 371-377.
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    abstract = "Nicotinamide (na) adducts of Co(II), Ni(II) and Zn(II) chlorides are synthesized and characterized by thermoanalytical methods (TG, DTG, DTA), FT IR (4000-400 cm-1) and UV/Vis spectroscopy. Structural similarity is inferred between the octahedral Co and Ni compounds of type [M(na)2(H2O)4]Cl2. The tetrahedral Zn complex [Zn(na)2Cl2] presents a different structure. The coordination of the metal ions in the Co and Ni adducts modelled by semiempirical theoretical methods compares well with the structural data for [Ni(na)2(H2O)4](NO)2·2H2 O.",
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    AU - Çakir, S.

    AU - Biçer, E.

    AU - Içbudak, H.

    AU - Naumov, Pance

    AU - Korkmaz, H.

    AU - Çakir, O.

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    AB - Nicotinamide (na) adducts of Co(II), Ni(II) and Zn(II) chlorides are synthesized and characterized by thermoanalytical methods (TG, DTG, DTA), FT IR (4000-400 cm-1) and UV/Vis spectroscopy. Structural similarity is inferred between the octahedral Co and Ni compounds of type [M(na)2(H2O)4]Cl2. The tetrahedral Zn complex [Zn(na)2Cl2] presents a different structure. The coordination of the metal ions in the Co and Ni adducts modelled by semiempirical theoretical methods compares well with the structural data for [Ni(na)2(H2O)4](NO)2·2H2 O.

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    KW - Nicotinamide adducts

    KW - Semiempirical calculations

    KW - Synthesis

    KW - UV/Vis spectra

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    JO - Polish Journal of Chemistry

    JF - Polish Journal of Chemistry

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