Synthesis and spectroscopic studies of novel Cu(II), Co(II), Ni(II) and Zn(II) mixed ligand complexes with saccharin and nicotinamide

S. Çakir, I. Bulut, Pance Naumov, E. Biçer, O. Çakir

Research output: Contribution to journalArticle

Abstract

Four novel mixed ligand complexes of Cu(II), Co(II), Ni(II) and Zn(II) with saccharin and nicotinamide were synthesised and characterised on the basis of elemental analysis, FT-IR spectroscopic study, UV-Vis spectrometric and magnetic susceptibility data. The structure of the Cu (II) complex is completely different from those of the Co(II), Ni(II) and Zn(II) complexes. From the frequencies of the saccharinato CO and SO2 modes, it has been proven that the saccharinato ligands in the structure of the Cu complex are coordinated to the metal ion ([Cu(NA)2(Sac)2(H2O)], where NA - nicotinamide, Sac - saccharinato ligand or ion), whilst in the Co(II), Ni(II) and Zn(II) complexes are uncoordinated and exist as ions ([M(NA)2(H2O)4](Sac)2).

Original languageEnglish (US)
Pages (from-to)1-7
Number of pages7
JournalJournal of Molecular Structure
Volume560
Issue number1-3
DOIs
StatePublished - Jan 29 2001

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Saccharin
Niacinamide
Ligands
Ions
Carbon Monoxide
Magnetic susceptibility
Metal ions
Chemical analysis

Keywords

  • FT-IR spectra
  • Nicotinamide complexes
  • Saccharinates
  • Structural interferences

ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Synthesis and spectroscopic studies of novel Cu(II), Co(II), Ni(II) and Zn(II) mixed ligand complexes with saccharin and nicotinamide. / Çakir, S.; Bulut, I.; Naumov, Pance; Biçer, E.; Çakir, O.

In: Journal of Molecular Structure, Vol. 560, No. 1-3, 29.01.2001, p. 1-7.

Research output: Contribution to journalArticle

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abstract = "Four novel mixed ligand complexes of Cu(II), Co(II), Ni(II) and Zn(II) with saccharin and nicotinamide were synthesised and characterised on the basis of elemental analysis, FT-IR spectroscopic study, UV-Vis spectrometric and magnetic susceptibility data. The structure of the Cu (II) complex is completely different from those of the Co(II), Ni(II) and Zn(II) complexes. From the frequencies of the saccharinato CO and SO2 modes, it has been proven that the saccharinato ligands in the structure of the Cu complex are coordinated to the metal ion ([Cu(NA)2(Sac)2(H2O)], where NA - nicotinamide, Sac - saccharinato ligand or ion), whilst in the Co(II), Ni(II) and Zn(II) complexes are uncoordinated and exist as ions ([M(NA)2(H2O)4](Sac)2).",
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AU - Çakir, S.

AU - Bulut, I.

AU - Naumov, Pance

AU - Biçer, E.

AU - Çakir, O.

PY - 2001/1/29

Y1 - 2001/1/29

N2 - Four novel mixed ligand complexes of Cu(II), Co(II), Ni(II) and Zn(II) with saccharin and nicotinamide were synthesised and characterised on the basis of elemental analysis, FT-IR spectroscopic study, UV-Vis spectrometric and magnetic susceptibility data. The structure of the Cu (II) complex is completely different from those of the Co(II), Ni(II) and Zn(II) complexes. From the frequencies of the saccharinato CO and SO2 modes, it has been proven that the saccharinato ligands in the structure of the Cu complex are coordinated to the metal ion ([Cu(NA)2(Sac)2(H2O)], where NA - nicotinamide, Sac - saccharinato ligand or ion), whilst in the Co(II), Ni(II) and Zn(II) complexes are uncoordinated and exist as ions ([M(NA)2(H2O)4](Sac)2).

AB - Four novel mixed ligand complexes of Cu(II), Co(II), Ni(II) and Zn(II) with saccharin and nicotinamide were synthesised and characterised on the basis of elemental analysis, FT-IR spectroscopic study, UV-Vis spectrometric and magnetic susceptibility data. The structure of the Cu (II) complex is completely different from those of the Co(II), Ni(II) and Zn(II) complexes. From the frequencies of the saccharinato CO and SO2 modes, it has been proven that the saccharinato ligands in the structure of the Cu complex are coordinated to the metal ion ([Cu(NA)2(Sac)2(H2O)], where NA - nicotinamide, Sac - saccharinato ligand or ion), whilst in the Co(II), Ni(II) and Zn(II) complexes are uncoordinated and exist as ions ([M(NA)2(H2O)4](Sac)2).

KW - FT-IR spectra

KW - Nicotinamide complexes

KW - Saccharinates

KW - Structural interferences

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