Abstract
A synthetic strategy toward the rapid synthesis and hydrolysis of poly(norbornene)/Poly(acrylic acid) graft copolymers using the combination of atom-transfer radical polymerization (ATRP) and ring-opening metathesis polymerization (ROMP), was discussed. The functional monomer design contains a polymerizable unit for ROMP, a side chain for ATRP initiation, and a linker between the side chain for ATRP initiation. The monomers were synthesized from 5-norbornene-2-carbonyl chloride through the condensation of either triethylene glycol monoethyl ether monomethyl ether. The results show that the combination of these two highly controlled polymerization methods allows for a modular approach toward the synthesis of graft copolymer.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 6644-6649 |
| Number of pages | 6 |
| Journal | Macromolecules |
| Volume | 37 |
| Issue number | 17 |
| DOIs | |
| State | Published - Aug 24 2004 |
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- Materials Chemistry
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Synthesis and hydrolysis of poly(norbornene)/poly(acrylic acid) graft copolymers synthesized via a combination of atom-transfer radical polymerization and ring-opening metathesis polymerization. / Kriegel, Robert M.; Rees, William S.; Weck, Marcus.
In: Macromolecules, Vol. 37, No. 17, 24.08.2004, p. 6644-6649.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis and hydrolysis of poly(norbornene)/poly(acrylic acid) graft copolymers synthesized via a combination of atom-transfer radical polymerization and ring-opening metathesis polymerization
AU - Kriegel, Robert M.
AU - Rees, William S.
AU - Weck, Marcus
PY - 2004/8/24
Y1 - 2004/8/24
N2 - A synthetic strategy toward the rapid synthesis and hydrolysis of poly(norbornene)/Poly(acrylic acid) graft copolymers using the combination of atom-transfer radical polymerization (ATRP) and ring-opening metathesis polymerization (ROMP), was discussed. The functional monomer design contains a polymerizable unit for ROMP, a side chain for ATRP initiation, and a linker between the side chain for ATRP initiation. The monomers were synthesized from 5-norbornene-2-carbonyl chloride through the condensation of either triethylene glycol monoethyl ether monomethyl ether. The results show that the combination of these two highly controlled polymerization methods allows for a modular approach toward the synthesis of graft copolymer.
AB - A synthetic strategy toward the rapid synthesis and hydrolysis of poly(norbornene)/Poly(acrylic acid) graft copolymers using the combination of atom-transfer radical polymerization (ATRP) and ring-opening metathesis polymerization (ROMP), was discussed. The functional monomer design contains a polymerizable unit for ROMP, a side chain for ATRP initiation, and a linker between the side chain for ATRP initiation. The monomers were synthesized from 5-norbornene-2-carbonyl chloride through the condensation of either triethylene glycol monoethyl ether monomethyl ether. The results show that the combination of these two highly controlled polymerization methods allows for a modular approach toward the synthesis of graft copolymer.
UR - http://www.scopus.com/inward/record.url?scp=4444237209&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=4444237209&partnerID=8YFLogxK
U2 - 10.1021/ma0358475
DO - 10.1021/ma0358475
M3 - Article
AN - SCOPUS:4444237209
VL - 37
SP - 6644
EP - 6649
JO - Macromolecules
JF - Macromolecules
SN - 0024-9297
IS - 17
ER -