Surface modified polymeric membranes to reduce (bio)fouling: A microbiological study using E. coli

Nidal Hilal, Victor Kochkodan, Laila Al-Khatib, Tetyana Levadna

Research output: Contribution to journalArticle

Abstract

Membrane (bio)fouling is the main problem during an operation of membrane elements for water treatment processes. In an attempt to reduce a bio(fouling) affinity, commercial polyvinilidene fluoride (PVDF) microfiltration membranes (Millipore) were surface modified via photoinitiated graft polymerisation with quatemized 2-(dimethylamino) ethyl metacrylate (gDMAEM) or 2-acrylamido-methyl-propane sulfonic acid (AMPS) as functional monomers. Membranes with different degrees of modification were obtained by varying the time of polymerisation and concentration of the monomer solution. Another set of PVDF membranes was modified using interfacial polymerisation between polyethyleneimine (PEI) and toluene diisocyanate. The affinity of modified membranes to biofouling was studied using E. coli bacteria. It was found that membrane samples modified with gDMAEM as well as with PEI have a strong bactericide effect towards E. coli. The possible mechanism of antimicrobial action of modified membranes has been discussed.

Original languageEnglish (US)
Pages (from-to)293-300
Number of pages8
JournalDesalination
Volume167
Issue number1-3
DOIs
StatePublished - Aug 15 2004

Fingerprint

Biofouling
Polymeric membranes
biofouling
Escherichia coli
membrane
Membranes
polymerization
Polyethyleneimine
Polymerization
Fluorides
fluoride
Monomers
Toluene 2,4-Diisocyanate
Bactericides
Propane
Microfiltration
Sulfonic Acids
propane
Water treatment
Grafts

Keywords

  • Antimicrobial action
  • Biofouling
  • Escherichia coli
  • Surface membrane modification

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Science(all)
  • Water Science and Technology
  • Mechanical Engineering

Cite this

Surface modified polymeric membranes to reduce (bio)fouling : A microbiological study using E. coli. / Hilal, Nidal; Kochkodan, Victor; Al-Khatib, Laila; Levadna, Tetyana.

In: Desalination, Vol. 167, No. 1-3, 15.08.2004, p. 293-300.

Research output: Contribution to journalArticle

Hilal, Nidal ; Kochkodan, Victor ; Al-Khatib, Laila ; Levadna, Tetyana. / Surface modified polymeric membranes to reduce (bio)fouling : A microbiological study using E. coli. In: Desalination. 2004 ; Vol. 167, No. 1-3. pp. 293-300.
@article{49cb9ae80a5b4d75a42e9f6853626dd2,
title = "Surface modified polymeric membranes to reduce (bio)fouling: A microbiological study using E. coli",
abstract = "Membrane (bio)fouling is the main problem during an operation of membrane elements for water treatment processes. In an attempt to reduce a bio(fouling) affinity, commercial polyvinilidene fluoride (PVDF) microfiltration membranes (Millipore) were surface modified via photoinitiated graft polymerisation with quatemized 2-(dimethylamino) ethyl metacrylate (gDMAEM) or 2-acrylamido-methyl-propane sulfonic acid (AMPS) as functional monomers. Membranes with different degrees of modification were obtained by varying the time of polymerisation and concentration of the monomer solution. Another set of PVDF membranes was modified using interfacial polymerisation between polyethyleneimine (PEI) and toluene diisocyanate. The affinity of modified membranes to biofouling was studied using E. coli bacteria. It was found that membrane samples modified with gDMAEM as well as with PEI have a strong bactericide effect towards E. coli. The possible mechanism of antimicrobial action of modified membranes has been discussed.",
keywords = "Antimicrobial action, Biofouling, Escherichia coli, Surface membrane modification",
author = "Nidal Hilal and Victor Kochkodan and Laila Al-Khatib and Tetyana Levadna",
year = "2004",
month = "8",
day = "15",
doi = "10.1016/j.desal.2004.06.138",
language = "English (US)",
volume = "167",
pages = "293--300",
journal = "Desalination",
issn = "0011-9164",
publisher = "Elsevier",
number = "1-3",

}

TY - JOUR

T1 - Surface modified polymeric membranes to reduce (bio)fouling

T2 - A microbiological study using E. coli

AU - Hilal, Nidal

AU - Kochkodan, Victor

AU - Al-Khatib, Laila

AU - Levadna, Tetyana

PY - 2004/8/15

Y1 - 2004/8/15

N2 - Membrane (bio)fouling is the main problem during an operation of membrane elements for water treatment processes. In an attempt to reduce a bio(fouling) affinity, commercial polyvinilidene fluoride (PVDF) microfiltration membranes (Millipore) were surface modified via photoinitiated graft polymerisation with quatemized 2-(dimethylamino) ethyl metacrylate (gDMAEM) or 2-acrylamido-methyl-propane sulfonic acid (AMPS) as functional monomers. Membranes with different degrees of modification were obtained by varying the time of polymerisation and concentration of the monomer solution. Another set of PVDF membranes was modified using interfacial polymerisation between polyethyleneimine (PEI) and toluene diisocyanate. The affinity of modified membranes to biofouling was studied using E. coli bacteria. It was found that membrane samples modified with gDMAEM as well as with PEI have a strong bactericide effect towards E. coli. The possible mechanism of antimicrobial action of modified membranes has been discussed.

AB - Membrane (bio)fouling is the main problem during an operation of membrane elements for water treatment processes. In an attempt to reduce a bio(fouling) affinity, commercial polyvinilidene fluoride (PVDF) microfiltration membranes (Millipore) were surface modified via photoinitiated graft polymerisation with quatemized 2-(dimethylamino) ethyl metacrylate (gDMAEM) or 2-acrylamido-methyl-propane sulfonic acid (AMPS) as functional monomers. Membranes with different degrees of modification were obtained by varying the time of polymerisation and concentration of the monomer solution. Another set of PVDF membranes was modified using interfacial polymerisation between polyethyleneimine (PEI) and toluene diisocyanate. The affinity of modified membranes to biofouling was studied using E. coli bacteria. It was found that membrane samples modified with gDMAEM as well as with PEI have a strong bactericide effect towards E. coli. The possible mechanism of antimicrobial action of modified membranes has been discussed.

KW - Antimicrobial action

KW - Biofouling

KW - Escherichia coli

KW - Surface membrane modification

UR - http://www.scopus.com/inward/record.url?scp=7544244510&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=7544244510&partnerID=8YFLogxK

U2 - 10.1016/j.desal.2004.06.138

DO - 10.1016/j.desal.2004.06.138

M3 - Article

AN - SCOPUS:7544244510

VL - 167

SP - 293

EP - 300

JO - Desalination

JF - Desalination

SN - 0011-9164

IS - 1-3

ER -