Surface-initiated polymerization on self-assembled monolayers: Effect of reaction conditions

Ursula Schmelmer, Anne Paul, Alexander Küller, Rainer Jordan, Armin Gölzhäuser, Michael Grunze, Abraham Ulman

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Self-assembled monolayers of 4′-nitro-4-mercaptobiphenyl were modified by electron beam irradiation and diazotization to create a surface-bond asymmetric azo initiator for the surface-initiated polymerization (SIP). The effect of different reaction conditions upon the thermally and photochemical initiated SIP was investigated.

Original languageEnglish (US)
Title of host publicationMacromolecular Symposia
Pages223-230
Number of pages8
Volume217
DOIs
StatePublished - Oct 2004

Fingerprint

Self assembled monolayers
Polymerization
Electron beams
Irradiation

Keywords

  • Azo initiator
  • Decomposition
  • Polymer brushes
  • Self-assembled monolayers
  • Surface-initiated polymerization

ASJC Scopus subject areas

  • Polymers and Plastics
  • Materials Chemistry

Cite this

Schmelmer, U., Paul, A., Küller, A., Jordan, R., Gölzhäuser, A., Grunze, M., & Ulman, A. (2004). Surface-initiated polymerization on self-assembled monolayers: Effect of reaction conditions. In Macromolecular Symposia (Vol. 217, pp. 223-230) https://doi.org/10.1002/masy.200451318

Surface-initiated polymerization on self-assembled monolayers : Effect of reaction conditions. / Schmelmer, Ursula; Paul, Anne; Küller, Alexander; Jordan, Rainer; Gölzhäuser, Armin; Grunze, Michael; Ulman, Abraham.

Macromolecular Symposia. Vol. 217 2004. p. 223-230.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Schmelmer, U, Paul, A, Küller, A, Jordan, R, Gölzhäuser, A, Grunze, M & Ulman, A 2004, Surface-initiated polymerization on self-assembled monolayers: Effect of reaction conditions. in Macromolecular Symposia. vol. 217, pp. 223-230. https://doi.org/10.1002/masy.200451318
Schmelmer U, Paul A, Küller A, Jordan R, Gölzhäuser A, Grunze M et al. Surface-initiated polymerization on self-assembled monolayers: Effect of reaction conditions. In Macromolecular Symposia. Vol. 217. 2004. p. 223-230 https://doi.org/10.1002/masy.200451318
Schmelmer, Ursula ; Paul, Anne ; Küller, Alexander ; Jordan, Rainer ; Gölzhäuser, Armin ; Grunze, Michael ; Ulman, Abraham. / Surface-initiated polymerization on self-assembled monolayers : Effect of reaction conditions. Macromolecular Symposia. Vol. 217 2004. pp. 223-230
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