Supramolecular Polymers

Elizabeth Elacqua, Niels Ten Brummelhuis, Marcus Weck

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

This chapter reviews main-chain- and side-chain-functionalized supramolecular polymers that were synthesized by ring-opening metathesis polymerization (ROMP) and acyclic diene metathesis (ADMET) polymerization. The polymers are assembled using directional supramolecular interactions, such as H-bonding, M-L coordination, and inclusion complexation, or a combination thereof. Supramolecular main-chain polymers can be formed using several methods. The simplest way is using a single type of monomer containing groups that can homo-dimerize. Side-chain-functionalized supramolecular polymers via olefin metathesis have emerged as modular targets, owing to the ability of metathesis to install a variety of desirable functional groups. Self-complementary H-bonding motifs have been utilized to form supramolecular polymers. Multifunctional supramolecular block copolymers have been prepared from the self-assembly of two end-group- and side-chain-functionalized polymers. Comprehending the self-assembly behavior of polyrotaxanes and exploiting noncovalent interactions can lead to the integration of internal motion (for example, translation, rotation, scissor-like motion) within supramolecular polymer frameworks.

Original languageEnglish (US)
Title of host publicationVolume 3
Subtitle of host publicationPolymer Synthesis
Publisherwiley
Pages71-92
Number of pages22
Volume3-3
ISBN (Electronic)9783527674107
ISBN (Print)9783527334247
DOIs
StatePublished - Jan 1 2015

Fingerprint

Polymers
Self assembly
Rotaxanes
Ring opening polymerization
Alkenes
Complexation
Functional groups
Block copolymers
Monomers
Polymerization

Keywords

  • Acyclic diene metathesis (ADMET) polymerization
  • Main-chain functionalized supramolecular polymers
  • Olefin metathesis
  • Ring-opening metathesis polymerization (ROMP)
  • Side-chain-functionalized supramolecular polymers

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Elacqua, E., Ten Brummelhuis, N., & Weck, M. (2015). Supramolecular Polymers. In Volume 3: Polymer Synthesis (Vol. 3-3, pp. 71-92). wiley. https://doi.org/10.1002/9783527674107.ch30

Supramolecular Polymers. / Elacqua, Elizabeth; Ten Brummelhuis, Niels; Weck, Marcus.

Volume 3: Polymer Synthesis. Vol. 3-3 wiley, 2015. p. 71-92.

Research output: Chapter in Book/Report/Conference proceedingChapter

Elacqua, E, Ten Brummelhuis, N & Weck, M 2015, Supramolecular Polymers. in Volume 3: Polymer Synthesis. vol. 3-3, wiley, pp. 71-92. https://doi.org/10.1002/9783527674107.ch30
Elacqua E, Ten Brummelhuis N, Weck M. Supramolecular Polymers. In Volume 3: Polymer Synthesis. Vol. 3-3. wiley. 2015. p. 71-92 https://doi.org/10.1002/9783527674107.ch30
Elacqua, Elizabeth ; Ten Brummelhuis, Niels ; Weck, Marcus. / Supramolecular Polymers. Volume 3: Polymer Synthesis. Vol. 3-3 wiley, 2015. pp. 71-92
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