Supramolecular click chemistry with a bisammonium-C60 substrate and a ditopic crown ether host

Uwe Hahn, Mourad Elhabiri, Ali Trabolsi, Haiko Herschbach, Emmanuelle Leize, Alain Van Dorsselaer, Anne Marie Albrecht-Gary, Jean François Nierengarten

    Research output: Contribution to journalArticle

    Abstract

    (Chemical Equation Presented) All clicking into place: Self-complementarity between a bis (crown ether) derivative and a bisammonium fullerene leads to the formation of a stable noncovalent macrocyclic 1:1 complex (see schematic representation). The binding constant for this complex is three orders of magnitude larger than that for other closely related systems as a result of the two-center host-guest topography.

    Original languageEnglish (US)
    Pages (from-to)5338-5341
    Number of pages4
    JournalAngewandte Chemie - International Edition
    Volume44
    Issue number33
    DOIs
    StatePublished - Aug 19 2005

    Fingerprint

    Supramolecular chemistry
    Crown Ethers
    Fullerenes
    Crown ethers
    Schematic diagrams
    Topography
    Derivatives
    Substrates

    Keywords

    • Binding studies
    • Crown compounds
    • Fullerenes
    • Host-guest systems
    • Supramolecular chemistry

    ASJC Scopus subject areas

    • Catalysis
    • Chemistry(all)

    Cite this

    Hahn, U., Elhabiri, M., Trabolsi, A., Herschbach, H., Leize, E., Van Dorsselaer, A., ... Nierengarten, J. F. (2005). Supramolecular click chemistry with a bisammonium-C60 substrate and a ditopic crown ether host. Angewandte Chemie - International Edition, 44(33), 5338-5341. https://doi.org/10.1002/anie.200501249

    Supramolecular click chemistry with a bisammonium-C60 substrate and a ditopic crown ether host. / Hahn, Uwe; Elhabiri, Mourad; Trabolsi, Ali; Herschbach, Haiko; Leize, Emmanuelle; Van Dorsselaer, Alain; Albrecht-Gary, Anne Marie; Nierengarten, Jean François.

    In: Angewandte Chemie - International Edition, Vol. 44, No. 33, 19.08.2005, p. 5338-5341.

    Research output: Contribution to journalArticle

    Hahn, U, Elhabiri, M, Trabolsi, A, Herschbach, H, Leize, E, Van Dorsselaer, A, Albrecht-Gary, AM & Nierengarten, JF 2005, 'Supramolecular click chemistry with a bisammonium-C60 substrate and a ditopic crown ether host', Angewandte Chemie - International Edition, vol. 44, no. 33, pp. 5338-5341. https://doi.org/10.1002/anie.200501249
    Hahn, Uwe ; Elhabiri, Mourad ; Trabolsi, Ali ; Herschbach, Haiko ; Leize, Emmanuelle ; Van Dorsselaer, Alain ; Albrecht-Gary, Anne Marie ; Nierengarten, Jean François. / Supramolecular click chemistry with a bisammonium-C60 substrate and a ditopic crown ether host. In: Angewandte Chemie - International Edition. 2005 ; Vol. 44, No. 33. pp. 5338-5341.
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