Subsecond morphological changes in nafion during water uptake detected by small-angle X-ray scattering

Ahmet Kusoglu, Miguel Modestino, Alexander Hexemer, Rachel A. Segalman, Adam Z. Weber

Research output: Contribution to journalArticle

Abstract

The ability of the Nafion membrane to absorb water rapidly and create a network of hydrated interconnected water domains provides this material with an unmatched ability to conduct ions through a chemically and mechanically robust membrane. The morphology and composition of these hydrated membranes significantly affects their transport properties and performance. This work demonstrates that differences in interfacial interactions between the membranes exposed to vapor or liquid water can cause significant changes in kinetics of water uptake. In situ small-angle X-ray scattering (SAXS) experiments captured the rapid swelling of the membrane in liquid water with a nanostructure rearrangement on the order of seconds. For membranes in contact with water vapor, morphological changes are four orders-of-magnitude slower than in liquid water, suggesting that interfacial resistance limits the penetration of water into the membrane. Also, upon water absorption from liquid water, a structural rearrangement from a distribution of spherical and cylindrical domains to exclusively cylindrical-like domains is suggested. These differences in water-uptake kinetics and morphology provide a new perspective into Schroeder's paradox, which dictates a different water content for vapor- and liquid-equilibrated ionomers at unit activity. The findings of this work provide critical insights into the fast kinetics of water absorption of the Nafion membrane, which can aid in the design of energy conversion devices that operate under frequent changes in environmental conditions.

Original languageEnglish (US)
Pages (from-to)33-36
Number of pages4
JournalACS Macro Letters
Volume1
Issue number1
DOIs
StatePublished - 2012

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X ray scattering
Membranes
Water
Liquids
Steam
Water absorption
Kinetics
Vapors
perfluorosulfonic acid
Ionomers
Energy conversion
Transport properties
Water vapor
Water content
Swelling
Nanostructures
Ions
Chemical analysis

ASJC Scopus subject areas

  • Organic Chemistry
  • Materials Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry

Cite this

Subsecond morphological changes in nafion during water uptake detected by small-angle X-ray scattering. / Kusoglu, Ahmet; Modestino, Miguel; Hexemer, Alexander; Segalman, Rachel A.; Weber, Adam Z.

In: ACS Macro Letters, Vol. 1, No. 1, 2012, p. 33-36.

Research output: Contribution to journalArticle

Kusoglu, Ahmet ; Modestino, Miguel ; Hexemer, Alexander ; Segalman, Rachel A. ; Weber, Adam Z. / Subsecond morphological changes in nafion during water uptake detected by small-angle X-ray scattering. In: ACS Macro Letters. 2012 ; Vol. 1, No. 1. pp. 33-36.
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