Spectroscopic and thermal studies of bis(N,N′-dimethylethylenediamine) and bis(N,N-dimethylethylenediamine)saccharinato complexes of Co(II), Ni(II), and Cu(II)

Okan Z. Yeşilel, Hasan Içbudak, Halis Ölmez, Pance Naumov

Research output: Contribution to journalArticle

Abstract

The mixed-ligand saccharin (Hsac) complexes of Co(II), Ni(II) and Cu(II) with N,N′-dimethylethylenediamine (dmen), and N,N-dimethylethylenediamine (ndmen) (Figure 1) were synthesized and characterized by elemental analysis, magnetic susceptibility, spectral (UV-Vis and FT-IR) methods, and simultaneous TG, DTG and DTA techniques. The complexes have pseudooctahedral geometries with two dimethylethylenediamine molecules coordinated to the metal ions as chelating ligands through their two nitrogen atoms and two monodentate saccharinato ligands in the trans positions for the complexes of the type [M(sac-O)2(dmen)2] (M = Co(II), Ni(II)), and [M(sac-N)2(ndmen)2] (M = Co(II), Ni(II), Cu(II)) and two aqua ligands in the trans positions in [Cu(H2O)2(dmen)2](sac)2. (sac-O; sac-N=the saccharinato ligand may be coordinated to the metal ions through their carbonyl oxygen or their nitrogen atom, respectively). The decomposition mechanism and thermal stability of the solid complexes are interpreted in terms of their structures. The thermal stability order of the investigated complexes is Cu(II)>Co(II)>Ni(II) while the bis(N,N′,-dimethylethylenediamine) complexes are thermally less stable than those of bis(N,N-dimethylethylenediamine). The final decomposition products - the respective metal oxides - were identified by FT-IR spectroscopy.

Original languageEnglish (US)
Pages (from-to)77-90
Number of pages14
JournalSynthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Volume33
Issue number1
DOIs
StatePublished - Jan 1 2003

Fingerprint

ligands
Ligands
nitrogen atoms
metal ions
thermal stability
decomposition
Metal ions
Thermodynamic stability
Nitrogen
metal oxides
Decomposition
thermal analysis
Saccharin
Atoms
Hot Temperature
dimethylethylenediamine
magnetic permeability
Chelation
Magnetic susceptibility
Differential thermal analysis

Keywords

  • N, N′-Dimethylethylenediamine
  • Saccharinato complexes
  • Thermal analysis
  • ve N, N-Dimethylethylenediamine

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

@article{820063e3b19c44e7b1890c91ae4854cc,
title = "Spectroscopic and thermal studies of bis(N,N′-dimethylethylenediamine) and bis(N,N-dimethylethylenediamine)saccharinato complexes of Co(II), Ni(II), and Cu(II)",
abstract = "The mixed-ligand saccharin (Hsac) complexes of Co(II), Ni(II) and Cu(II) with N,N′-dimethylethylenediamine (dmen), and N,N-dimethylethylenediamine (ndmen) (Figure 1) were synthesized and characterized by elemental analysis, magnetic susceptibility, spectral (UV-Vis and FT-IR) methods, and simultaneous TG, DTG and DTA techniques. The complexes have pseudooctahedral geometries with two dimethylethylenediamine molecules coordinated to the metal ions as chelating ligands through their two nitrogen atoms and two monodentate saccharinato ligands in the trans positions for the complexes of the type [M(sac-O)2(dmen)2] (M = Co(II), Ni(II)), and [M(sac-N)2(ndmen)2] (M = Co(II), Ni(II), Cu(II)) and two aqua ligands in the trans positions in [Cu(H2O)2(dmen)2](sac)2. (sac-O; sac-N=the saccharinato ligand may be coordinated to the metal ions through their carbonyl oxygen or their nitrogen atom, respectively). The decomposition mechanism and thermal stability of the solid complexes are interpreted in terms of their structures. The thermal stability order of the investigated complexes is Cu(II)>Co(II)>Ni(II) while the bis(N,N′,-dimethylethylenediamine) complexes are thermally less stable than those of bis(N,N-dimethylethylenediamine). The final decomposition products - the respective metal oxides - were identified by FT-IR spectroscopy.",
keywords = "N, N′-Dimethylethylenediamine, Saccharinato complexes, Thermal analysis, ve N, N-Dimethylethylenediamine",
author = "Yeşilel, {Okan Z.} and Hasan I{\cc}budak and Halis {\"O}lmez and Pance Naumov",
year = "2003",
month = "1",
day = "1",
doi = "10.1081/SIM-120016874",
language = "English (US)",
volume = "33",
pages = "77--90",
journal = "Inorganic and Nano-Metal Chemistry",
issn = "2470-1556",
publisher = "Taylor and Francis Ltd.",
number = "1",

}

TY - JOUR

T1 - Spectroscopic and thermal studies of bis(N,N′-dimethylethylenediamine) and bis(N,N-dimethylethylenediamine)saccharinato complexes of Co(II), Ni(II), and Cu(II)

AU - Yeşilel, Okan Z.

AU - Içbudak, Hasan

AU - Ölmez, Halis

AU - Naumov, Pance

PY - 2003/1/1

Y1 - 2003/1/1

N2 - The mixed-ligand saccharin (Hsac) complexes of Co(II), Ni(II) and Cu(II) with N,N′-dimethylethylenediamine (dmen), and N,N-dimethylethylenediamine (ndmen) (Figure 1) were synthesized and characterized by elemental analysis, magnetic susceptibility, spectral (UV-Vis and FT-IR) methods, and simultaneous TG, DTG and DTA techniques. The complexes have pseudooctahedral geometries with two dimethylethylenediamine molecules coordinated to the metal ions as chelating ligands through their two nitrogen atoms and two monodentate saccharinato ligands in the trans positions for the complexes of the type [M(sac-O)2(dmen)2] (M = Co(II), Ni(II)), and [M(sac-N)2(ndmen)2] (M = Co(II), Ni(II), Cu(II)) and two aqua ligands in the trans positions in [Cu(H2O)2(dmen)2](sac)2. (sac-O; sac-N=the saccharinato ligand may be coordinated to the metal ions through their carbonyl oxygen or their nitrogen atom, respectively). The decomposition mechanism and thermal stability of the solid complexes are interpreted in terms of their structures. The thermal stability order of the investigated complexes is Cu(II)>Co(II)>Ni(II) while the bis(N,N′,-dimethylethylenediamine) complexes are thermally less stable than those of bis(N,N-dimethylethylenediamine). The final decomposition products - the respective metal oxides - were identified by FT-IR spectroscopy.

AB - The mixed-ligand saccharin (Hsac) complexes of Co(II), Ni(II) and Cu(II) with N,N′-dimethylethylenediamine (dmen), and N,N-dimethylethylenediamine (ndmen) (Figure 1) were synthesized and characterized by elemental analysis, magnetic susceptibility, spectral (UV-Vis and FT-IR) methods, and simultaneous TG, DTG and DTA techniques. The complexes have pseudooctahedral geometries with two dimethylethylenediamine molecules coordinated to the metal ions as chelating ligands through their two nitrogen atoms and two monodentate saccharinato ligands in the trans positions for the complexes of the type [M(sac-O)2(dmen)2] (M = Co(II), Ni(II)), and [M(sac-N)2(ndmen)2] (M = Co(II), Ni(II), Cu(II)) and two aqua ligands in the trans positions in [Cu(H2O)2(dmen)2](sac)2. (sac-O; sac-N=the saccharinato ligand may be coordinated to the metal ions through their carbonyl oxygen or their nitrogen atom, respectively). The decomposition mechanism and thermal stability of the solid complexes are interpreted in terms of their structures. The thermal stability order of the investigated complexes is Cu(II)>Co(II)>Ni(II) while the bis(N,N′,-dimethylethylenediamine) complexes are thermally less stable than those of bis(N,N-dimethylethylenediamine). The final decomposition products - the respective metal oxides - were identified by FT-IR spectroscopy.

KW - N, N′-Dimethylethylenediamine

KW - Saccharinato complexes

KW - Thermal analysis

KW - ve N, N-Dimethylethylenediamine

UR - http://www.scopus.com/inward/record.url?scp=0037219747&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037219747&partnerID=8YFLogxK

U2 - 10.1081/SIM-120016874

DO - 10.1081/SIM-120016874

M3 - Article

AN - SCOPUS:0037219747

VL - 33

SP - 77

EP - 90

JO - Inorganic and Nano-Metal Chemistry

JF - Inorganic and Nano-Metal Chemistry

SN - 2470-1556

IS - 1

ER -