Skeletal rearrangements induced by chemical ionization-I. Analogy to solvolysis1 1 NCL Communication No. 2434.

G. Sudhakar Reddy, M. Vairamani, K. G. Das, H. budzikiewicz, Mark M. Green

Research output: Contribution to journalArticle

Abstract

In contrast to the usual expectation in chemical ionization (CI) mass spectrometry, the CI spectra of a series of aryl 4-nitro-Δ'-cyclohexenes show very low intensity protonated molecular ions while a major share of the ion current is carried by rearrangement ions. The intervention of a rearrangement long known in the solvolysis of cyclohexenyl carbenium ions can account for the observed CI behaviour.

Original languageEnglish (US)
Pages (from-to)2697-2701
Number of pages5
JournalTetrahedron
Volume35
Issue number22
DOIs
StatePublished - 1979

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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