Site-selective metal-coordination-based patterning of silane monolayers

Minfeng Li, Yu Wang, Victor Piñon, Marcus Weck

Research output: Contribution to journalArticle

Abstract

Herein, we report a method to pattern a derivatized nifedipine silane monolayer that aromatizes under UV irradiation. Using a functionalized SCS-Pd(ii) pincer complex, we demonstrate that a strong metal-coordination complex between the aromatized nifedipine derivative and the pincer complex is formed. This methodology integrates SAM photolithography (top-down) and molecular recognition directed self-assembly (bottom-up) strategies to create simple and rapid synthesizable functional patterned surfaces.

Original languageEnglish (US)
Pages (from-to)2802-2804
Number of pages3
JournalChemical Communications
Volume47
Issue number10
DOIs
StatePublished - Mar 14 2011

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Silanes
Molecular recognition
Photolithography
Nifedipine
Self assembly
Monolayers
Metals
Irradiation
Derivatives
Coordination Complexes

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Site-selective metal-coordination-based patterning of silane monolayers. / Li, Minfeng; Wang, Yu; Piñon, Victor; Weck, Marcus.

In: Chemical Communications, Vol. 47, No. 10, 14.03.2011, p. 2802-2804.

Research output: Contribution to journalArticle

Li, Minfeng ; Wang, Yu ; Piñon, Victor ; Weck, Marcus. / Site-selective metal-coordination-based patterning of silane monolayers. In: Chemical Communications. 2011 ; Vol. 47, No. 10. pp. 2802-2804.
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