Side-chain functionalized polymers containing bipyridine coordination sites: Polymerization and metal-coordination studies

Joseph R. Carlise, Marcus Weck

Research output: Contribution to journalArticle

Abstract

Monomers containing (trisbipyridine) ruthenium(II), (bisbipyridine) palladium(II), and heteroleptic ruthenium complexes were synthesized and polymerized via ruthenium-catalyzed ring-opening metathesis polymerization in nonpolar solvents. The solubility of the resulting polyelectrolytes in nonpolar solutions could be tuned by alkyl functionalization of the Uganda around the metal centers. These polymers are the first polynorbornenes containing a 2,2′-bipyridine-based metal complex at each repeating unit and might be used in numerous applications, including luminescent and electroluminescent materials.

Original languageEnglish (US)
Pages (from-to)2973-2984
Number of pages12
JournalJournal of Polymer Science, Part A: Polymer Chemistry
Volume42
Issue number12
DOIs
StatePublished - Jun 15 2004

Fingerprint

Ruthenium
Polymers
Metals
Polymerization
Coordination Complexes
Ring opening polymerization
Palladium
Metal complexes
Polyelectrolytes
Solubility
Monomers

Keywords

  • Bipyridine
  • Coordination polymer
  • ROMP
  • Supramolecular structures
  • Transition metal chemistry

ASJC Scopus subject areas

  • Polymers and Plastics
  • Materials Chemistry

Cite this

@article{4fcc0074f0094c398c847a5279fadd6d,
title = "Side-chain functionalized polymers containing bipyridine coordination sites: Polymerization and metal-coordination studies",
abstract = "Monomers containing (trisbipyridine) ruthenium(II), (bisbipyridine) palladium(II), and heteroleptic ruthenium complexes were synthesized and polymerized via ruthenium-catalyzed ring-opening metathesis polymerization in nonpolar solvents. The solubility of the resulting polyelectrolytes in nonpolar solutions could be tuned by alkyl functionalization of the Uganda around the metal centers. These polymers are the first polynorbornenes containing a 2,2′-bipyridine-based metal complex at each repeating unit and might be used in numerous applications, including luminescent and electroluminescent materials.",
keywords = "Bipyridine, Coordination polymer, ROMP, Supramolecular structures, Transition metal chemistry",
author = "Carlise, {Joseph R.} and Marcus Weck",
year = "2004",
month = "6",
day = "15",
doi = "10.1002/pola.20134",
language = "English (US)",
volume = "42",
pages = "2973--2984",
journal = "Journal of Polymer Science, Part A: Polymer Chemistry",
issn = "0887-624X",
publisher = "John Wiley and Sons Inc.",
number = "12",

}

TY - JOUR

T1 - Side-chain functionalized polymers containing bipyridine coordination sites

T2 - Polymerization and metal-coordination studies

AU - Carlise, Joseph R.

AU - Weck, Marcus

PY - 2004/6/15

Y1 - 2004/6/15

N2 - Monomers containing (trisbipyridine) ruthenium(II), (bisbipyridine) palladium(II), and heteroleptic ruthenium complexes were synthesized and polymerized via ruthenium-catalyzed ring-opening metathesis polymerization in nonpolar solvents. The solubility of the resulting polyelectrolytes in nonpolar solutions could be tuned by alkyl functionalization of the Uganda around the metal centers. These polymers are the first polynorbornenes containing a 2,2′-bipyridine-based metal complex at each repeating unit and might be used in numerous applications, including luminescent and electroluminescent materials.

AB - Monomers containing (trisbipyridine) ruthenium(II), (bisbipyridine) palladium(II), and heteroleptic ruthenium complexes were synthesized and polymerized via ruthenium-catalyzed ring-opening metathesis polymerization in nonpolar solvents. The solubility of the resulting polyelectrolytes in nonpolar solutions could be tuned by alkyl functionalization of the Uganda around the metal centers. These polymers are the first polynorbornenes containing a 2,2′-bipyridine-based metal complex at each repeating unit and might be used in numerous applications, including luminescent and electroluminescent materials.

KW - Bipyridine

KW - Coordination polymer

KW - ROMP

KW - Supramolecular structures

KW - Transition metal chemistry

UR - http://www.scopus.com/inward/record.url?scp=2942582471&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=2942582471&partnerID=8YFLogxK

U2 - 10.1002/pola.20134

DO - 10.1002/pola.20134

M3 - Article

AN - SCOPUS:2942582471

VL - 42

SP - 2973

EP - 2984

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

SN - 0887-624X

IS - 12

ER -