Separated quadrupolar field experiment

Rajeev Kumar, Wen Ling, Wolfgang Schoefberger, Alexej Jerschow

Research output: Contribution to journalArticle

Abstract

We describe an NMR experiment that produces spectra correlating the first-order quadrupolar spectrum and the central transition spectrum of half-integer quadrupolar spins, allowing one to separate the quadrupolar parameters in overlapping spectra under both static and magic-angle-spinning conditions. Promising fields of applications include situations where the sample cannot easily be rotated, or where it cannot be rotated at the magic angle.

Original languageEnglish (US)
Pages (from-to)209-213
Number of pages5
JournalJournal of Magnetic Resonance
Volume172
Issue number2
DOIs
StatePublished - Feb 2005

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Magic angle spinning
Nuclear magnetic resonance
Experiments
metal spinning
integers
nuclear magnetic resonance

Keywords

  • Ex situ NMR
  • MQMAS
  • Quadrupolar coupling
  • Quadrupolar nuclei
  • Static solid-state NMR

ASJC Scopus subject areas

  • Molecular Biology
  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Radiology Nuclear Medicine and imaging
  • Condensed Matter Physics

Cite this

Separated quadrupolar field experiment. / Kumar, Rajeev; Ling, Wen; Schoefberger, Wolfgang; Jerschow, Alexej.

In: Journal of Magnetic Resonance, Vol. 172, No. 2, 02.2005, p. 209-213.

Research output: Contribution to journalArticle

Kumar, Rajeev ; Ling, Wen ; Schoefberger, Wolfgang ; Jerschow, Alexej. / Separated quadrupolar field experiment. In: Journal of Magnetic Resonance. 2005 ; Vol. 172, No. 2. pp. 209-213.
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