Scaling law for the liquid to soft solid transition kinetics in a block copolymer melt

N. P. Balsara, W. O. Kim, J. H. Lee, M. Y. Chang, B. A. Garetz, M. C. Newstein, S. S. Patel

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

Experimental data for the kinetics of order formation in a polystyrene-polyisopropene block copolymer melt is presented, limiting the attention to small quench depths, ε. The temperature dependence of molecular mobility was obtained from independent rheological measurements. The ε dependence of the rate of growth of ordered domains dl/dt was demonstrated, after correcting for changes in molecular mobility, exhibits power law behavior, with an exponent of about 2.

Original languageEnglish (US)
Title of host publicationAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
PublisherACS
Pages1007
Number of pages1
Volume40
Edition2
StatePublished - 1999

Fingerprint

Scaling laws
Polystyrenes
Block copolymers
Kinetics
Liquids
Temperature

ASJC Scopus subject areas

  • Polymers and Plastics

Cite this

Balsara, N. P., Kim, W. O., Lee, J. H., Chang, M. Y., Garetz, B. A., Newstein, M. C., & Patel, S. S. (1999). Scaling law for the liquid to soft solid transition kinetics in a block copolymer melt. In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry (2 ed., Vol. 40, pp. 1007). ACS.

Scaling law for the liquid to soft solid transition kinetics in a block copolymer melt. / Balsara, N. P.; Kim, W. O.; Lee, J. H.; Chang, M. Y.; Garetz, B. A.; Newstein, M. C.; Patel, S. S.

American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. Vol. 40 2. ed. ACS, 1999. p. 1007.

Research output: Chapter in Book/Report/Conference proceedingChapter

Balsara, NP, Kim, WO, Lee, JH, Chang, MY, Garetz, BA, Newstein, MC & Patel, SS 1999, Scaling law for the liquid to soft solid transition kinetics in a block copolymer melt. in American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 2 edn, vol. 40, ACS, pp. 1007.
Balsara NP, Kim WO, Lee JH, Chang MY, Garetz BA, Newstein MC et al. Scaling law for the liquid to soft solid transition kinetics in a block copolymer melt. In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 2 ed. Vol. 40. ACS. 1999. p. 1007
Balsara, N. P. ; Kim, W. O. ; Lee, J. H. ; Chang, M. Y. ; Garetz, B. A. ; Newstein, M. C. ; Patel, S. S. / Scaling law for the liquid to soft solid transition kinetics in a block copolymer melt. American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. Vol. 40 2. ed. ACS, 1999. pp. 1007
@inbook{dfadf5af0c58423faebdfbd9e62239e8,
title = "Scaling law for the liquid to soft solid transition kinetics in a block copolymer melt",
abstract = "Experimental data for the kinetics of order formation in a polystyrene-polyisopropene block copolymer melt is presented, limiting the attention to small quench depths, ε. The temperature dependence of molecular mobility was obtained from independent rheological measurements. The ε dependence of the rate of growth of ordered domains dl/dt was demonstrated, after correcting for changes in molecular mobility, exhibits power law behavior, with an exponent of about 2.",
author = "Balsara, {N. P.} and Kim, {W. O.} and Lee, {J. H.} and Chang, {M. Y.} and Garetz, {B. A.} and Newstein, {M. C.} and Patel, {S. S.}",
year = "1999",
language = "English (US)",
volume = "40",
pages = "1007",
booktitle = "American Chemical Society, Polymer Preprints, Division of Polymer Chemistry",
publisher = "ACS",
edition = "2",

}

TY - CHAP

T1 - Scaling law for the liquid to soft solid transition kinetics in a block copolymer melt

AU - Balsara, N. P.

AU - Kim, W. O.

AU - Lee, J. H.

AU - Chang, M. Y.

AU - Garetz, B. A.

AU - Newstein, M. C.

AU - Patel, S. S.

PY - 1999

Y1 - 1999

N2 - Experimental data for the kinetics of order formation in a polystyrene-polyisopropene block copolymer melt is presented, limiting the attention to small quench depths, ε. The temperature dependence of molecular mobility was obtained from independent rheological measurements. The ε dependence of the rate of growth of ordered domains dl/dt was demonstrated, after correcting for changes in molecular mobility, exhibits power law behavior, with an exponent of about 2.

AB - Experimental data for the kinetics of order formation in a polystyrene-polyisopropene block copolymer melt is presented, limiting the attention to small quench depths, ε. The temperature dependence of molecular mobility was obtained from independent rheological measurements. The ε dependence of the rate of growth of ordered domains dl/dt was demonstrated, after correcting for changes in molecular mobility, exhibits power law behavior, with an exponent of about 2.

UR - http://www.scopus.com/inward/record.url?scp=33744893636&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33744893636&partnerID=8YFLogxK

M3 - Chapter

VL - 40

SP - 1007

BT - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

PB - ACS

ER -