RuCl2[(2,6-Me2C6H3)PPh 2]2: A new precursor for cyclometalated ruthenium(II) complexes

Walter Baratta, Alessandro Del Zotto, Gennaro Esposito, Alessandra Sechi, Micaela Toniutti, Ennio Zangrando, Pierluigi Rigo

Research output: Contribution to journalArticle

Abstract

The five-coordinate complex RuCl{(2-CH2-6-MeC6H 3)PPh2}(CO)(L*) (2; L* = (2,6-Me 2C6H3)-PPh2) was prepared in high yield by reaction of the 14-electron complex RuCl2(L*) 2 (1) with formaldehyde in the presence of NEt3 via cyclometalation of an ortho methyl group and aldehyde decarbonylation. Alternatively, 2 can be obtained from RuCl3 hydrate, L*, H 2CO, and amine in a one-pot reaction. Treatment of 2 with CO affords the cis-dicarbonyl derivative RuCl{(2-CH2-6-MeC6H 3)PPh2}(CO)2(L*) (3), whereas reaction with phosphines leads to the five- and six-coordinate complexes RuCl{(2-CH 2-6-MeC6H3)PPh2}(CO)(L)n (n = 1, L = PCy3 (4), Ph2P(CH2) 3PPh2 (6); n = 2, L = PMePh2 (5)) by displacement of L*, according to the steric requirement of the incoming ligand. Similarly, complex 2 reacts with the bidentate nitrogen ligands 2-(aminomethyl)pyridine and ethylenediamine, affording the six-coordinate derivatives RuCl{(2-CH2-6-MeC6H3)PPh 2}(CO)(L) (L = 2-(aminomethyl)pyridine (7), ethylenediamine (8)) in high yield. The related iodide derivative RuI{(2-CH2-6-MeC 6H3)PPh2}-(CO)(L*) (9) has been prepared from 2 and NaI by chloride displacement. Treatment of 2 with Na[BAr 4f] in the presence of 2,2'-bipyridine or 2-(aminomethyl)pyridine gives the cationic complexes [Ru{(2-CH 2-6-MeC6H3)PPh2}(CO)(L*)(L)] [BAr4f] (L = 2,2'-bipyridine (10), 2-(aminomethyl)pyridine (11)), while with 3 equiv of pyridine the derivative [Ru{(2-CH 2-6-MeC6H)3)-PPh2}(CO)(Py) 3][BAr4f] (12) is obtained. The structure of the δ-agostic complex 2 has been established through an X-ray crystal study, whereas the structure for 7 is supported by 2D NMR experiments in solution. Complexes 7 and 8 are active catalysts for transfer hydrogenation of ketones in 2-propanol, displaying TOP values up to 63 000 h-1.

Original languageEnglish (US)
Pages (from-to)6264-6272
Number of pages9
JournalOrganometallics
Volume23
Issue number26
DOIs
StatePublished - Dec 20 2004

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Ruthenium
Carbon Monoxide
ruthenium
pyridines
ethylenediamine
methylidyne
Derivatives
2,2'-Dipyridyl
ligands
formaldehyde
aldehydes
phosphines
ketones
hydrates
iodides
hydrogenation
Phosphines
Ligands
amines
chlorides

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Baratta, W., Zotto, A. D., Esposito, G., Sechi, A., Toniutti, M., Zangrando, E., & Rigo, P. (2004). RuCl2[(2,6-Me2C6H3)PPh 2]2: A new precursor for cyclometalated ruthenium(II) complexes. Organometallics, 23(26), 6264-6272. https://doi.org/10.1021/om0494081

RuCl2[(2,6-Me2C6H3)PPh 2]2 : A new precursor for cyclometalated ruthenium(II) complexes. / Baratta, Walter; Zotto, Alessandro Del; Esposito, Gennaro; Sechi, Alessandra; Toniutti, Micaela; Zangrando, Ennio; Rigo, Pierluigi.

In: Organometallics, Vol. 23, No. 26, 20.12.2004, p. 6264-6272.

Research output: Contribution to journalArticle

Baratta, W, Zotto, AD, Esposito, G, Sechi, A, Toniutti, M, Zangrando, E & Rigo, P 2004, 'RuCl2[(2,6-Me2C6H3)PPh 2]2: A new precursor for cyclometalated ruthenium(II) complexes', Organometallics, vol. 23, no. 26, pp. 6264-6272. https://doi.org/10.1021/om0494081
Baratta, Walter ; Zotto, Alessandro Del ; Esposito, Gennaro ; Sechi, Alessandra ; Toniutti, Micaela ; Zangrando, Ennio ; Rigo, Pierluigi. / RuCl2[(2,6-Me2C6H3)PPh 2]2 : A new precursor for cyclometalated ruthenium(II) complexes. In: Organometallics. 2004 ; Vol. 23, No. 26. pp. 6264-6272.
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title = "RuCl2[(2,6-Me2C6H3)PPh 2]2: A new precursor for cyclometalated ruthenium(II) complexes",
abstract = "The five-coordinate complex RuCl{(2-CH2-6-MeC6H 3)PPh2}(CO)(L*) (2; L* = (2,6-Me 2C6H3)-PPh2) was prepared in high yield by reaction of the 14-electron complex RuCl2(L*) 2 (1) with formaldehyde in the presence of NEt3 via cyclometalation of an ortho methyl group and aldehyde decarbonylation. Alternatively, 2 can be obtained from RuCl3 hydrate, L*, H 2CO, and amine in a one-pot reaction. Treatment of 2 with CO affords the cis-dicarbonyl derivative RuCl{(2-CH2-6-MeC6H 3)PPh2}(CO)2(L*) (3), whereas reaction with phosphines leads to the five- and six-coordinate complexes RuCl{(2-CH 2-6-MeC6H3)PPh2}(CO)(L)n (n = 1, L = PCy3 (4), Ph2P(CH2) 3PPh2 (6); n = 2, L = PMePh2 (5)) by displacement of L*, according to the steric requirement of the incoming ligand. Similarly, complex 2 reacts with the bidentate nitrogen ligands 2-(aminomethyl)pyridine and ethylenediamine, affording the six-coordinate derivatives RuCl{(2-CH2-6-MeC6H3)PPh 2}(CO)(L) (L = 2-(aminomethyl)pyridine (7), ethylenediamine (8)) in high yield. The related iodide derivative RuI{(2-CH2-6-MeC 6H3)PPh2}-(CO)(L*) (9) has been prepared from 2 and NaI by chloride displacement. Treatment of 2 with Na[BAr 4f] in the presence of 2,2'-bipyridine or 2-(aminomethyl)pyridine gives the cationic complexes [Ru{(2-CH 2-6-MeC6H3)PPh2}(CO)(L*)(L)] [BAr4f] (L = 2,2'-bipyridine (10), 2-(aminomethyl)pyridine (11)), while with 3 equiv of pyridine the derivative [Ru{(2-CH 2-6-MeC6H)3)-PPh2}(CO)(Py) 3][BAr4f] (12) is obtained. The structure of the δ-agostic complex 2 has been established through an X-ray crystal study, whereas the structure for 7 is supported by 2D NMR experiments in solution. Complexes 7 and 8 are active catalysts for transfer hydrogenation of ketones in 2-propanol, displaying TOP values up to 63 000 h-1.",
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T1 - RuCl2[(2,6-Me2C6H3)PPh 2]2

T2 - A new precursor for cyclometalated ruthenium(II) complexes

AU - Baratta, Walter

AU - Zotto, Alessandro Del

AU - Esposito, Gennaro

AU - Sechi, Alessandra

AU - Toniutti, Micaela

AU - Zangrando, Ennio

AU - Rigo, Pierluigi

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N2 - The five-coordinate complex RuCl{(2-CH2-6-MeC6H 3)PPh2}(CO)(L*) (2; L* = (2,6-Me 2C6H3)-PPh2) was prepared in high yield by reaction of the 14-electron complex RuCl2(L*) 2 (1) with formaldehyde in the presence of NEt3 via cyclometalation of an ortho methyl group and aldehyde decarbonylation. Alternatively, 2 can be obtained from RuCl3 hydrate, L*, H 2CO, and amine in a one-pot reaction. Treatment of 2 with CO affords the cis-dicarbonyl derivative RuCl{(2-CH2-6-MeC6H 3)PPh2}(CO)2(L*) (3), whereas reaction with phosphines leads to the five- and six-coordinate complexes RuCl{(2-CH 2-6-MeC6H3)PPh2}(CO)(L)n (n = 1, L = PCy3 (4), Ph2P(CH2) 3PPh2 (6); n = 2, L = PMePh2 (5)) by displacement of L*, according to the steric requirement of the incoming ligand. Similarly, complex 2 reacts with the bidentate nitrogen ligands 2-(aminomethyl)pyridine and ethylenediamine, affording the six-coordinate derivatives RuCl{(2-CH2-6-MeC6H3)PPh 2}(CO)(L) (L = 2-(aminomethyl)pyridine (7), ethylenediamine (8)) in high yield. The related iodide derivative RuI{(2-CH2-6-MeC 6H3)PPh2}-(CO)(L*) (9) has been prepared from 2 and NaI by chloride displacement. Treatment of 2 with Na[BAr 4f] in the presence of 2,2'-bipyridine or 2-(aminomethyl)pyridine gives the cationic complexes [Ru{(2-CH 2-6-MeC6H3)PPh2}(CO)(L*)(L)] [BAr4f] (L = 2,2'-bipyridine (10), 2-(aminomethyl)pyridine (11)), while with 3 equiv of pyridine the derivative [Ru{(2-CH 2-6-MeC6H)3)-PPh2}(CO)(Py) 3][BAr4f] (12) is obtained. The structure of the δ-agostic complex 2 has been established through an X-ray crystal study, whereas the structure for 7 is supported by 2D NMR experiments in solution. Complexes 7 and 8 are active catalysts for transfer hydrogenation of ketones in 2-propanol, displaying TOP values up to 63 000 h-1.

AB - The five-coordinate complex RuCl{(2-CH2-6-MeC6H 3)PPh2}(CO)(L*) (2; L* = (2,6-Me 2C6H3)-PPh2) was prepared in high yield by reaction of the 14-electron complex RuCl2(L*) 2 (1) with formaldehyde in the presence of NEt3 via cyclometalation of an ortho methyl group and aldehyde decarbonylation. Alternatively, 2 can be obtained from RuCl3 hydrate, L*, H 2CO, and amine in a one-pot reaction. Treatment of 2 with CO affords the cis-dicarbonyl derivative RuCl{(2-CH2-6-MeC6H 3)PPh2}(CO)2(L*) (3), whereas reaction with phosphines leads to the five- and six-coordinate complexes RuCl{(2-CH 2-6-MeC6H3)PPh2}(CO)(L)n (n = 1, L = PCy3 (4), Ph2P(CH2) 3PPh2 (6); n = 2, L = PMePh2 (5)) by displacement of L*, according to the steric requirement of the incoming ligand. Similarly, complex 2 reacts with the bidentate nitrogen ligands 2-(aminomethyl)pyridine and ethylenediamine, affording the six-coordinate derivatives RuCl{(2-CH2-6-MeC6H3)PPh 2}(CO)(L) (L = 2-(aminomethyl)pyridine (7), ethylenediamine (8)) in high yield. The related iodide derivative RuI{(2-CH2-6-MeC 6H3)PPh2}-(CO)(L*) (9) has been prepared from 2 and NaI by chloride displacement. Treatment of 2 with Na[BAr 4f] in the presence of 2,2'-bipyridine or 2-(aminomethyl)pyridine gives the cationic complexes [Ru{(2-CH 2-6-MeC6H3)PPh2}(CO)(L*)(L)] [BAr4f] (L = 2,2'-bipyridine (10), 2-(aminomethyl)pyridine (11)), while with 3 equiv of pyridine the derivative [Ru{(2-CH 2-6-MeC6H)3)-PPh2}(CO)(Py) 3][BAr4f] (12) is obtained. The structure of the δ-agostic complex 2 has been established through an X-ray crystal study, whereas the structure for 7 is supported by 2D NMR experiments in solution. Complexes 7 and 8 are active catalysts for transfer hydrogenation of ketones in 2-propanol, displaying TOP values up to 63 000 h-1.

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