Reversible photomechanical switching of individual engineered molecules at a metallic surface

Matthew J. Comstock, Niv Levy, Armen Kirakosian, Jongweon Cho, Frank Lauterwasser, Jessica H. Harvey, David A. Strubbe, Jean M.J. Fréchet, Dirk Trauner, Steven G. Louie, Michael F. Crommie

Research output: Contribution to journalArticle

Abstract

We have observed reversible light-induced mechanical switching for individual organic molecules bound to a metal surface. Scanning tunneling microscopy (STM) was used to image the features of individual azobenzene molecules on Au(111) before and after reversibly cycling their mechanical structure between trans and cis states using light. Azobenzene molecules were engineered to increase their surface photomechanical activity by attaching varying numbers of tert-butyl (TB) ligands ("legs") to the azobenzene phenyl rings. STM images show that increasing the number of TB legs "lifts" the azobenzene molecules from the substrate, thereby increasing molecular photomechanical activity by decreasing molecule-surface coupling.

Original languageEnglish (US)
Article number038301
JournalPhysical Review Letters
Volume99
Issue number3
DOIs
StatePublished - Jul 18 2007

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molecules
scanning tunneling microscopy
metal surfaces
ligands
cycles
rings

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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Comstock, M. J., Levy, N., Kirakosian, A., Cho, J., Lauterwasser, F., Harvey, J. H., ... Crommie, M. F. (2007). Reversible photomechanical switching of individual engineered molecules at a metallic surface. Physical Review Letters, 99(3), [038301]. https://doi.org/10.1103/PhysRevLett.99.038301

Reversible photomechanical switching of individual engineered molecules at a metallic surface. / Comstock, Matthew J.; Levy, Niv; Kirakosian, Armen; Cho, Jongweon; Lauterwasser, Frank; Harvey, Jessica H.; Strubbe, David A.; Fréchet, Jean M.J.; Trauner, Dirk; Louie, Steven G.; Crommie, Michael F.

In: Physical Review Letters, Vol. 99, No. 3, 038301, 18.07.2007.

Research output: Contribution to journalArticle

Comstock, MJ, Levy, N, Kirakosian, A, Cho, J, Lauterwasser, F, Harvey, JH, Strubbe, DA, Fréchet, JMJ, Trauner, D, Louie, SG & Crommie, MF 2007, 'Reversible photomechanical switching of individual engineered molecules at a metallic surface', Physical Review Letters, vol. 99, no. 3, 038301. https://doi.org/10.1103/PhysRevLett.99.038301
Comstock, Matthew J. ; Levy, Niv ; Kirakosian, Armen ; Cho, Jongweon ; Lauterwasser, Frank ; Harvey, Jessica H. ; Strubbe, David A. ; Fréchet, Jean M.J. ; Trauner, Dirk ; Louie, Steven G. ; Crommie, Michael F. / Reversible photomechanical switching of individual engineered molecules at a metallic surface. In: Physical Review Letters. 2007 ; Vol. 99, No. 3.
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