Redox inversion of helicity in propeller-shaped molecules derived from S-methyl cysteine and methioninol

Homar S. Barcena, Andrea E. Holmes, Steffen Zahn, James Canary

Research output: Contribution to journalArticle

Abstract

(Figure presented) One-electron reduction inverts the helicity of copper complexes formed from derivatives of S-methylcysteine and methioninol. The change in conformation of the organic ligand is followed in the exciton-coupled circular dichroism (ECCD) spectra of the complexes.

Original languageEnglish (US)
Pages (from-to)709-711
Number of pages3
JournalOrganic Letters
Volume5
Issue number5
DOIs
StatePublished - Mar 6 2003

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propellers
cysteine
Propellers
Circular Dichroism
dichroism
Oxidation-Reduction
Conformations
Copper
excitons
Electrons
inversions
Ligands
Derivatives
copper
ligands
Molecules
molecules
electrons
methioninol
S-methylcysteine

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

Redox inversion of helicity in propeller-shaped molecules derived from S-methyl cysteine and methioninol. / Barcena, Homar S.; Holmes, Andrea E.; Zahn, Steffen; Canary, James.

In: Organic Letters, Vol. 5, No. 5, 06.03.2003, p. 709-711.

Research output: Contribution to journalArticle

Barcena, Homar S. ; Holmes, Andrea E. ; Zahn, Steffen ; Canary, James. / Redox inversion of helicity in propeller-shaped molecules derived from S-methyl cysteine and methioninol. In: Organic Letters. 2003 ; Vol. 5, No. 5. pp. 709-711.
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