Recognition of imidazoles by strapped zinc(II) porphyrin receptors: Insight into the induced-fit mechanism

Jeremy Brandel, Ali Trabolsi, Frédéric Melin, Mourad Elhabiri, Jean Weiss, Anne Marie Albrecht-Gary

Research output: Contribution to journalArticle

Abstract

Imidazole-porphyrin coordination has become an important tool in the design of self-assembled materials. A combination of spectrophotometric and stopped-flow techniques has been used to gain insight into the control of imidazole binding in the distal pocket of phenanthroline-strapped porphyrins. The binding studies of a variety of imidazole substrates in combination with both hindered and accessible receptors have permitted the determination of the thermodynamic and kinetic parameters associated with the imidazole binding.

Original languageEnglish (US)
Pages (from-to)9534-9536
Number of pages3
JournalInorganic Chemistry
Volume46
Issue number23
DOIs
StatePublished - Nov 12 2007

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Imidazoles
Porphyrins
imidazoles
porphyrins
Zinc
zinc
Phenanthrolines
Kinetic parameters
Thermodynamics
thermodynamics
imidazole
kinetics
Substrates

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Recognition of imidazoles by strapped zinc(II) porphyrin receptors : Insight into the induced-fit mechanism. / Brandel, Jeremy; Trabolsi, Ali; Melin, Frédéric; Elhabiri, Mourad; Weiss, Jean; Albrecht-Gary, Anne Marie.

In: Inorganic Chemistry, Vol. 46, No. 23, 12.11.2007, p. 9534-9536.

Research output: Contribution to journalArticle

Brandel, Jeremy ; Trabolsi, Ali ; Melin, Frédéric ; Elhabiri, Mourad ; Weiss, Jean ; Albrecht-Gary, Anne Marie. / Recognition of imidazoles by strapped zinc(II) porphyrin receptors : Insight into the induced-fit mechanism. In: Inorganic Chemistry. 2007 ; Vol. 46, No. 23. pp. 9534-9536.
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