Post-synthetic modifications of cadmium-based knots and links

Thirumurugan Prakasam, Rana A. Bilbeisi, Matteo Lusi, John Carl Olsen, Carlos Platas-Iglesias, Ali Trabolsi

    Research output: Contribution to journalArticle

    Abstract

    Three topologically non-trivial cadmium(ii)-based complexes - Cd-[2]C, Cd-TK and Cd-SL - were simultaneously self-assembled in a dynamic library, individually isolated and fully characterized using solid-state, gas-phase and solution-phase techniques. Post-synthetic modifications, including reduction and transmetalation, were subsequently achieved. Imine bond reduction followed by demetallation led to the isolation of the corresponding organic molecules [2]C, TK and SL. Transmetalation of Cd-TK and Cd-SL with the zinc(ii) cation resulted in isolation of the corresponding zinc(ii)-containing complexes Zn-TK and Zn-SL.

    Original languageEnglish (US)
    Pages (from-to)7398-7401
    Number of pages4
    JournalChemical Communications
    Volume52
    Issue number46
    DOIs
    StatePublished - Jan 1 2016

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    Cadmium
    Zinc
    Imines
    Cations
    Gases
    Positive ions
    Molecules

    ASJC Scopus subject areas

    • Catalysis
    • Electronic, Optical and Magnetic Materials
    • Ceramics and Composites
    • Chemistry(all)
    • Surfaces, Coatings and Films
    • Metals and Alloys
    • Materials Chemistry

    Cite this

    Prakasam, T., Bilbeisi, R. A., Lusi, M., Olsen, J. C., Platas-Iglesias, C., & Trabolsi, A. (2016). Post-synthetic modifications of cadmium-based knots and links. Chemical Communications, 52(46), 7398-7401. https://doi.org/10.1039/c6cc02423h

    Post-synthetic modifications of cadmium-based knots and links. / Prakasam, Thirumurugan; Bilbeisi, Rana A.; Lusi, Matteo; Olsen, John Carl; Platas-Iglesias, Carlos; Trabolsi, Ali.

    In: Chemical Communications, Vol. 52, No. 46, 01.01.2016, p. 7398-7401.

    Research output: Contribution to journalArticle

    Prakasam, T, Bilbeisi, RA, Lusi, M, Olsen, JC, Platas-Iglesias, C & Trabolsi, A 2016, 'Post-synthetic modifications of cadmium-based knots and links', Chemical Communications, vol. 52, no. 46, pp. 7398-7401. https://doi.org/10.1039/c6cc02423h
    Prakasam T, Bilbeisi RA, Lusi M, Olsen JC, Platas-Iglesias C, Trabolsi A. Post-synthetic modifications of cadmium-based knots and links. Chemical Communications. 2016 Jan 1;52(46):7398-7401. https://doi.org/10.1039/c6cc02423h
    Prakasam, Thirumurugan ; Bilbeisi, Rana A. ; Lusi, Matteo ; Olsen, John Carl ; Platas-Iglesias, Carlos ; Trabolsi, Ali. / Post-synthetic modifications of cadmium-based knots and links. In: Chemical Communications. 2016 ; Vol. 52, No. 46. pp. 7398-7401.
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