Porous anisotropic metal nanostructures through controlled transmetallation across a dialysis membrane

Sourabh Shukla, Renu Pasricha, Murali Sastry

Research output: Contribution to journalArticle

Abstract

Nanostructured metals with hollow interiors are of technological importance due to their unique optoelectronic properties and enhanced surface area. We describe herein, a novel method for the synthesis of anisotropic gold and palladium nanoparticles through a simple galvanic replacement reaction across a semi-permeable dialysis membrane. The control over the reaction kinetics achieved by the presence of membrane enables one to tune the bimetal composition, particle porosity and morphology. Rapid outward diffusion of silver ions generated from the sacrificial silver nanoparticles even at room temperatures prevents the precipitation of high quantities of silver chloride, thereby circumventing the need for product purification. The porous anisotropic nanostructures have potential applications in catalysis, cell imaging and therapeutics.

Original languageEnglish (US)
Pages (from-to)6401-6408
Number of pages8
JournalJournal of Nanoscience and Nanotechnology
Volume9
Issue number11
DOIs
StatePublished - Nov 1 2009

Fingerprint

Dialysis membranes
dialysis
Nanostructures
Silver
Nanoparticles
Dialysis
Metals
silver
bimetals
membranes
Bimetals
silver chlorides
nanoparticles
Membranes
Surface Properties
Porosity
Palladium
Catalysis
purification
Reaction kinetics

Keywords

  • Ag/Pd nanostructures
  • Anisotropic nanoparticles
  • Dialysis
  • Galvanic replacement
  • Porous nanostructures
  • Silver nanotriangles
  • Silver nanowires
  • Transmetallation

ASJC Scopus subject areas

  • Bioengineering
  • Chemistry(all)
  • Biomedical Engineering
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Porous anisotropic metal nanostructures through controlled transmetallation across a dialysis membrane. / Shukla, Sourabh; Pasricha, Renu; Sastry, Murali.

In: Journal of Nanoscience and Nanotechnology, Vol. 9, No. 11, 01.11.2009, p. 6401-6408.

Research output: Contribution to journalArticle

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