Polymer coating of vanadium oxide nanowires to improve cathodic capacity in lithium batteries

Forrest S. Gittleson, Jonathan Hwang, Ryan C. Sekol, Andre Taylor

Research output: Contribution to journalArticle

Abstract

Vanadium oxide is a promising next generation cathode material in lithium-based batteries because of its high theoretical energy density. To address the shortcomings of V2O5, which include poor electrical conductivity and stability upon cycling, a core-shell structure consisting of high aspect ratio V2O5 nanowires coated with electroactive polyaniline (PANI) was synthesized. The two step solution-based process involved a facile hydrothermal synthesis of one dimensional V 2O5 and subsequent in situ polymerization on the active material surface. Conformal coatings of PANI were achieved at a range of compositions (21-51% by weight) by altering the polymerization conditions. The composite nanowire structure was shown to benefit cycle stability, demonstrating a 90% improvement in discharge capacity over the uncoated wires after 40 cycles at increasing rates of charge. Improvements in rate capability were also correlated with increasing percentages of PANI in the composite, where the 51% PANI composite demonstrated a 57% increase in capacity over an uncoated sample at the high rate of 440 mA g-1 (1 C). Here, we present evidence from galvanostatic cycling experiments that an electroactive polymer coating can enhance the underlying capacity of a cathode material.

Original languageEnglish (US)
Pages (from-to)7979-7984
Number of pages6
JournalJournal of Materials Chemistry A
Volume1
Issue number27
DOIs
StatePublished - Jul 19 2013

Fingerprint

Vanadium
Lithium batteries
Polyaniline
Oxides
Nanowires
Polymers
Coatings
Composite materials
Cathodes
Polymerization
Hydrothermal synthesis
Lithium
Aspect ratio
Wire
polyaniline
Chemical analysis
Experiments
vanadium pentoxide

ASJC Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

Polymer coating of vanadium oxide nanowires to improve cathodic capacity in lithium batteries. / Gittleson, Forrest S.; Hwang, Jonathan; Sekol, Ryan C.; Taylor, Andre.

In: Journal of Materials Chemistry A, Vol. 1, No. 27, 19.07.2013, p. 7979-7984.

Research output: Contribution to journalArticle

Gittleson, Forrest S. ; Hwang, Jonathan ; Sekol, Ryan C. ; Taylor, Andre. / Polymer coating of vanadium oxide nanowires to improve cathodic capacity in lithium batteries. In: Journal of Materials Chemistry A. 2013 ; Vol. 1, No. 27. pp. 7979-7984.
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