Polyisocyanates and the Interplay of Experiment and Theory in the Formation of Lyotropic Cholesteric States

Takahiro Sato, Yoshihiro Sato, Yoshimi Umemura, Akio Teramoto, Yoshikazu Nagamura, Jürgen Wagner, Dexi Weng, Yoshio Okamoto, Koichi Hatada, Mark M. Green

Research output: Contribution to journalArticle

Abstract

We have made the first observations of the lyotropic cholesteric liquid crystal state of polyisocyanates, in which a synthetically controlled range of the dynamic excesses of one helical sense offer new opportunities for study in the area. In poly((R)-2,6-dimethylheptyl isocyanate) we have generated the cholesteric lyotropic state and studied the pitch as a function of solvent, temperature, and concentration. These data were broken down into entropie, Sq, and enthalpic, Hq terms and were compared to theoretical predictions. The data for the polyisocyanate were compared to those already known for poly(γ-benzyl L-glutamate) and schizophyllaii. For all three helical polymers, the sign of Sq agrees with Straley's screw model, allowing an absolute assignment of macromolecular helical sense from liquid crystal properties. The nematic phase of the dynamically racemic poly(n-hexyl isocyanate) was doped with a derivative of a steroid and of menthol, and the resulting cholesteric pitch was studied as a function of temperature and dope concentration. The failure to fit these data to theoretical expectations applicable to intrinsically chiral polymers may be due to a sensitivity of the helix sense ratio of the macromolecule to the chiral characteristics of the cholesteric phase.

Original languageEnglish (US)
Pages (from-to)4551-4559
Number of pages9
JournalMacromolecules
Volume26
Issue number17
DOIs
StatePublished - Jan 1 1993

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ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Sato, T., Sato, Y., Umemura, Y., Teramoto, A., Nagamura, Y., Wagner, J., Weng, D., Okamoto, Y., Hatada, K., & Green, M. M. (1993). Polyisocyanates and the Interplay of Experiment and Theory in the Formation of Lyotropic Cholesteric States. Macromolecules, 26(17), 4551-4559. https://doi.org/10.1021/ma00069a021