Photoinduced phase transition of the coordinationally unsaturated d 9 metal centers of bis(N,N-diethylethylenediamine)copper(II) perchlorate within the thermal hysteresis of the spin-exchange interaction

Pance Naumov, Kenji Sakurai, Toru Asaka, Alexei A. Belik, Shin Ichi Adachi, Junichi Takahashi, Shin Ya Koshihara

    Research output: Contribution to journalArticle

    Abstract

    Diffraction evidence is presented that the structure of one-dimensional arrays of strained, coordinationally unsaturated d9 pseudo-Jahn-Teller centers of bis(N,N-diethylethylenediamine)copper(II) perchlorate is affected by excitation of the LMCT bands within the hysteresis region of a low-temperature ferromagnetic-to-antiferromagnetic phase transition.

    Original languageEnglish (US)
    Pages (from-to)1345-1347
    Number of pages3
    JournalEuropean Journal of Inorganic Chemistry
    Issue number7
    DOIs
    StatePublished - Apr 3 2006

    Fingerprint

    Exchange interactions
    Hysteresis
    Diffraction
    Phase transitions
    Metals
    Temperature
    Hot Temperature
    copper(II) perchlorate
    N,N-diethylethylenediamine

    Keywords

    • Jahn-Teller effect
    • Photochromism
    • Photodiffraction
    • Photoinduced phase transitions
    • Thermochromism

    ASJC Scopus subject areas

    • Inorganic Chemistry

    Cite this

    Photoinduced phase transition of the coordinationally unsaturated d 9 metal centers of bis(N,N-diethylethylenediamine)copper(II) perchlorate within the thermal hysteresis of the spin-exchange interaction. / Naumov, Pance; Sakurai, Kenji; Asaka, Toru; Belik, Alexei A.; Adachi, Shin Ichi; Takahashi, Junichi; Koshihara, Shin Ya.

    In: European Journal of Inorganic Chemistry, No. 7, 03.04.2006, p. 1345-1347.

    Research output: Contribution to journalArticle

    Naumov, Pance ; Sakurai, Kenji ; Asaka, Toru ; Belik, Alexei A. ; Adachi, Shin Ichi ; Takahashi, Junichi ; Koshihara, Shin Ya. / Photoinduced phase transition of the coordinationally unsaturated d 9 metal centers of bis(N,N-diethylethylenediamine)copper(II) perchlorate within the thermal hysteresis of the spin-exchange interaction. In: European Journal of Inorganic Chemistry. 2006 ; No. 7. pp. 1345-1347.
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    abstract = "Diffraction evidence is presented that the structure of one-dimensional arrays of strained, coordinationally unsaturated d9 pseudo-Jahn-Teller centers of bis(N,N-diethylethylenediamine)copper(II) perchlorate is affected by excitation of the LMCT bands within the hysteresis region of a low-temperature ferromagnetic-to-antiferromagnetic phase transition.",
    keywords = "Jahn-Teller effect, Photochromism, Photodiffraction, Photoinduced phase transitions, Thermochromism",
    author = "Pance Naumov and Kenji Sakurai and Toru Asaka and Belik, {Alexei A.} and Adachi, {Shin Ichi} and Junichi Takahashi and Koshihara, {Shin Ya}",
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    TY - JOUR

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    AU - Naumov, Pance

    AU - Sakurai, Kenji

    AU - Asaka, Toru

    AU - Belik, Alexei A.

    AU - Adachi, Shin Ichi

    AU - Takahashi, Junichi

    AU - Koshihara, Shin Ya

    PY - 2006/4/3

    Y1 - 2006/4/3

    N2 - Diffraction evidence is presented that the structure of one-dimensional arrays of strained, coordinationally unsaturated d9 pseudo-Jahn-Teller centers of bis(N,N-diethylethylenediamine)copper(II) perchlorate is affected by excitation of the LMCT bands within the hysteresis region of a low-temperature ferromagnetic-to-antiferromagnetic phase transition.

    AB - Diffraction evidence is presented that the structure of one-dimensional arrays of strained, coordinationally unsaturated d9 pseudo-Jahn-Teller centers of bis(N,N-diethylethylenediamine)copper(II) perchlorate is affected by excitation of the LMCT bands within the hysteresis region of a low-temperature ferromagnetic-to-antiferromagnetic phase transition.

    KW - Jahn-Teller effect

    KW - Photochromism

    KW - Photodiffraction

    KW - Photoinduced phase transitions

    KW - Thermochromism

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