Phase transfer of platinum nanoparticles from aqueous to organic solutions using fatty amine molecules

Ashavani Kumar, Hrushikesh M. Joshi, Anandrao B. Mandale, Rajendra Srivastava, Suguna D. Adyanthaya, Renu Pasricha, Murali Sastry

Research output: Contribution to journalArticle

Abstract

In this report we demonstrate a simple process based on amine chemistry for the phase transfer of platinum nanoparticles from an aqueous to an organic solution. The phase transfer was accomplished by vigorous shaking of a biphasic mixture of platinum nanoparticles synthesised in an aqueous medium and octadecylamine (ODA) in hexane. During shaking of the biphasic mixture, the aqueous platinum nanoparticles complex via either coordination bond formation or weak covalent interaction with the ODA molecules present in the organic phase. This process renders the nanoparticles sufficiently hydrophobic and dispersible in the organic phase. The ODA-stabilised platinum nanoparticles could be separated out from hexane in the form of a powder that is readily redispersible in weakly polar and non-polar organic solvents. The ODA-capped platinum nanoparticles show high catalytic activity in hydrogenation reactions and this is demonstrated in the efficient conversion of styrene to ethyl benzene. The nature of binding of the ODA molecules to the platinum nanoparticles surface was characterised by thermogravimetry, transmission electron microscopy (TEM), X-ray photoemission spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR).

Original languageEnglish (US)
Pages (from-to)293-300
Number of pages8
JournalJournal of Chemical Sciences
Volume116
Issue number5
DOIs
StatePublished - Jan 1 2004

Fingerprint

Platinum
Amines
Nanoparticles
Molecules
Hexanes
Styrene
Ethylbenzene
Photoelectron spectroscopy
X ray spectroscopy
Powders
Organic solvents
Hydrogenation
Thermogravimetric analysis
Catalyst activity
stearylamine
Transmission electron microscopy

Keywords

  • Hydrophobization
  • Nanoparticles
  • Phase transfer
  • Platinum
  • X-ray photoemission spectroscopy

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Phase transfer of platinum nanoparticles from aqueous to organic solutions using fatty amine molecules. / Kumar, Ashavani; Joshi, Hrushikesh M.; Mandale, Anandrao B.; Srivastava, Rajendra; Adyanthaya, Suguna D.; Pasricha, Renu; Sastry, Murali.

In: Journal of Chemical Sciences, Vol. 116, No. 5, 01.01.2004, p. 293-300.

Research output: Contribution to journalArticle

Kumar, A, Joshi, HM, Mandale, AB, Srivastava, R, Adyanthaya, SD, Pasricha, R & Sastry, M 2004, 'Phase transfer of platinum nanoparticles from aqueous to organic solutions using fatty amine molecules', Journal of Chemical Sciences, vol. 116, no. 5, pp. 293-300. https://doi.org/10.1007/BF02708280
Kumar, Ashavani ; Joshi, Hrushikesh M. ; Mandale, Anandrao B. ; Srivastava, Rajendra ; Adyanthaya, Suguna D. ; Pasricha, Renu ; Sastry, Murali. / Phase transfer of platinum nanoparticles from aqueous to organic solutions using fatty amine molecules. In: Journal of Chemical Sciences. 2004 ; Vol. 116, No. 5. pp. 293-300.
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