Palladium nanostructures from multi-component metallic glass

Sundeep Mukherjee, Marcelo Carmo, Golden Kumar, Ryan C. Sekol, André D. Taylor, Jan Schroers

Research output: Contribution to journalArticle

Abstract

Dendritic palladium nanostructures are obtained from Ni 60Pd 20P 17B 3 metallic glass by cyclic voltammetry in sulfuric acid. The length-scale and growth kinetics of the dendrites are dictated by the self-assembling template formed during electro-dissolution of the alloy constituents, but can alternatively be manipulated using the metallic glass in the form of a suitable nano-pattern template. The morphology evolution, surface chemistry, and electro-catalytic behavior of the dendrites are discussed. These branched palladium-rich dendrites show high activity for carbon monoxide and methanol oxidation in an alkaline medium, suggesting their potential use as high-performance catalysts in direct alcohol fuel cells.

Original languageEnglish (US)
Pages (from-to)145-150
Number of pages6
JournalElectrochimica Acta
Volume74
DOIs
StatePublished - Jul 15 2012

Keywords

  • Catalysis
  • Dendrite
  • Metallic glass
  • Nanostructure
  • Palladium

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Electrochemistry

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    Mukherjee, S., Carmo, M., Kumar, G., Sekol, R. C., Taylor, A. D., & Schroers, J. (2012). Palladium nanostructures from multi-component metallic glass. Electrochimica Acta, 74, 145-150. https://doi.org/10.1016/j.electacta.2012.04.038