Optical rotation of achiral pentaerythritol

Kacey Claborn, Javier Herreros Cedres, Christine Isborn, Alexey Zozulya, Edgar Weckert, Werner Kaminsky, Bart Kahr

Research output: Contribution to journalArticle

Abstract

The optical rotatory power of achiral crystals of achiral pentaerythritol molecules was measured. The maximum rotations were found to be ±6°/mm. The quantum mechanically computed rotation of pentaerythritol molecules using linear response theory was 6 times larger although the experimental and theoretical tensors were similarly oriented to within 5°.

Original languageEnglish (US)
Pages (from-to)14746-14747
Number of pages2
JournalJournal of the American Chemical Society
Volume128
Issue number46
DOIs
StatePublished - Nov 22 2006

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Optical rotation
Optical Rotation
Molecules
Tensors
Crystals
pentaerythritol

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Claborn, K., Cedres, J. H., Isborn, C., Zozulya, A., Weckert, E., Kaminsky, W., & Kahr, B. (2006). Optical rotation of achiral pentaerythritol. Journal of the American Chemical Society, 128(46), 14746-14747. https://doi.org/10.1021/ja064631q

Optical rotation of achiral pentaerythritol. / Claborn, Kacey; Cedres, Javier Herreros; Isborn, Christine; Zozulya, Alexey; Weckert, Edgar; Kaminsky, Werner; Kahr, Bart.

In: Journal of the American Chemical Society, Vol. 128, No. 46, 22.11.2006, p. 14746-14747.

Research output: Contribution to journalArticle

Claborn, K, Cedres, JH, Isborn, C, Zozulya, A, Weckert, E, Kaminsky, W & Kahr, B 2006, 'Optical rotation of achiral pentaerythritol', Journal of the American Chemical Society, vol. 128, no. 46, pp. 14746-14747. https://doi.org/10.1021/ja064631q
Claborn K, Cedres JH, Isborn C, Zozulya A, Weckert E, Kaminsky W et al. Optical rotation of achiral pentaerythritol. Journal of the American Chemical Society. 2006 Nov 22;128(46):14746-14747. https://doi.org/10.1021/ja064631q
Claborn, Kacey ; Cedres, Javier Herreros ; Isborn, Christine ; Zozulya, Alexey ; Weckert, Edgar ; Kaminsky, Werner ; Kahr, Bart. / Optical rotation of achiral pentaerythritol. In: Journal of the American Chemical Society. 2006 ; Vol. 128, No. 46. pp. 14746-14747.
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