Nanoimprinting sub-100 nm features in a photovoltaic nanocomposite using durable bulk metallic glass molds

Jonathan P. Singer, Manesh Gopinadhan, Zhen Shao, Andre Taylor, Jan Schroers, Chinedum O. Osuji

Research output: Contribution to journalArticle

Abstract

The use of bulk metallic glass (BMG) for the nanoimprint of high-aspect-ratio (>3) features into functional polymers is investigated. To accomplish this, the most critical aspect is the successful demolding of the imprinted polymer. By fluorosilane functionalization of the BMG surface and optimization of processing temperature, high aspect pore features down to 45 nm diameters are introduced into the surface of two organic photovoltaic systems: poly(3-hexylthiophene-2,5-diyl) (P3HT) and 1:1 mixtures of P3HT with Phenyl-C61-butyric acid methyl ester (PCBM). The crystallinity of P3HT demands higher forming temperatures and pressures that are difficult to obtain with conventional soft nanoimprint lithography molds. The ability to accommodate a wide range of processing conditions and the low cost of fabricating molds with nanometer-scale features point to the large potential of nanotextured BMGs as an economical and scalable imprint material for high-resolution applications.

Original languageEnglish (US)
Pages (from-to)3456-3461
Number of pages6
JournalACS Applied Materials and Interfaces
Volume7
Issue number6
DOIs
StatePublished - Jan 1 2015

Fingerprint

Metallic glass
Molds
Nanocomposites
Nanoimprint lithography
Functional polymers
Butyric acid
Butyric Acid
Processing
Aspect ratio
Esters
Polymers
Temperature
Costs
poly(3-hexylthiophene-2,5-diyl)

Keywords

  • bulk heterojunctions
  • bulk metallic glass
  • nanoimprint lithography
  • organic photovoltaics
  • polymer patterning

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Nanoimprinting sub-100 nm features in a photovoltaic nanocomposite using durable bulk metallic glass molds. / Singer, Jonathan P.; Gopinadhan, Manesh; Shao, Zhen; Taylor, Andre; Schroers, Jan; Osuji, Chinedum O.

In: ACS Applied Materials and Interfaces, Vol. 7, No. 6, 01.01.2015, p. 3456-3461.

Research output: Contribution to journalArticle

Singer, Jonathan P. ; Gopinadhan, Manesh ; Shao, Zhen ; Taylor, Andre ; Schroers, Jan ; Osuji, Chinedum O. / Nanoimprinting sub-100 nm features in a photovoltaic nanocomposite using durable bulk metallic glass molds. In: ACS Applied Materials and Interfaces. 2015 ; Vol. 7, No. 6. pp. 3456-3461.
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