Molecular recognition and the design of solid state structures

Protonation-induced conformational change and self-assembly of 2,6-diamidopyridinium phosphates

Steven J. Geib, Simon C. Hirst, Cristina Vicent, Andrew Hamilton

Research output: Contribution to journalArticle

Abstract

Protonation of 2,6-diamidopyridine with diaryl phosphates leads to a conformational change in the pyridine from inwardly to outwardly directed amide-NH groups and a resultant self-assembly of the anion and cation into an alternating cocrystal with a novel hydrogen bonding motif.

Original languageEnglish (US)
Pages (from-to)1283-1285
Number of pages3
JournalJournal of the Chemical Society D: Chemical Communications
Issue number18
DOIs
StatePublished - 1991

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Molecular recognition
Protonation
Hydrogen Bonding
Amides
Pyridine
Self assembly
Anions
Cations
Hydrogen bonds
Phosphates
Negative ions
Positive ions
pyridine
diamidopyridine
lead phosphate

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

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title = "Molecular recognition and the design of solid state structures: Protonation-induced conformational change and self-assembly of 2,6-diamidopyridinium phosphates",
abstract = "Protonation of 2,6-diamidopyridine with diaryl phosphates leads to a conformational change in the pyridine from inwardly to outwardly directed amide-NH groups and a resultant self-assembly of the anion and cation into an alternating cocrystal with a novel hydrogen bonding motif.",
author = "Geib, {Steven J.} and Hirst, {Simon C.} and Cristina Vicent and Andrew Hamilton",
year = "1991",
doi = "10.1039/C39910001283",
language = "English (US)",
pages = "1283--1285",
journal = "Chemical Communications",
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publisher = "Royal Society of Chemistry",
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T2 - Protonation-induced conformational change and self-assembly of 2,6-diamidopyridinium phosphates

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AU - Hirst, Simon C.

AU - Vicent, Cristina

AU - Hamilton, Andrew

PY - 1991

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AB - Protonation of 2,6-diamidopyridine with diaryl phosphates leads to a conformational change in the pyridine from inwardly to outwardly directed amide-NH groups and a resultant self-assembly of the anion and cation into an alternating cocrystal with a novel hydrogen bonding motif.

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