Mixed self-assembled multilayer of 4,4′-dimercaptobiphenyl and 1,8-octanedithiol

Tina Louise Brower, Myneeka Cook, Abraham Ulman

Research output: Contribution to journalArticle

Abstract

Mixed multilayers from aromatic (biphenyl) and aliphatic (octane) dithiols, using Cu(II) ions, have been prepared and characterized by ellipsometry, FTIR, and XPS. The data support the formation of multilayers in which interlayer disulfide linkages connect the 4,4′-dimercaptobiphenyl layers and intralayer disulfide bonds connect 1,8-octanedithiol molecules. Cu(I) ions connect the aromatic and alipathic layers.

Original languageEnglish (US)
Pages (from-to)11721-11725
Number of pages5
JournalJournal of Physical Chemistry B
Volume107
Issue number42
StatePublished - Oct 23 2003

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disulfides
Disulfides
Multilayers
Ions
Ellipsometry
octanes
thiols
linkages
ellipsometry
interlayers
ions
X ray photoelectron spectroscopy
Molecules
molecules
1,8-octanedithiol
diphenyl
dithiol
octane

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Mixed self-assembled multilayer of 4,4′-dimercaptobiphenyl and 1,8-octanedithiol. / Brower, Tina Louise; Cook, Myneeka; Ulman, Abraham.

In: Journal of Physical Chemistry B, Vol. 107, No. 42, 23.10.2003, p. 11721-11725.

Research output: Contribution to journalArticle

Brower, Tina Louise ; Cook, Myneeka ; Ulman, Abraham. / Mixed self-assembled multilayer of 4,4′-dimercaptobiphenyl and 1,8-octanedithiol. In: Journal of Physical Chemistry B. 2003 ; Vol. 107, No. 42. pp. 11721-11725.
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