Metal-catalyzed silylene insertions of allylic ethers

Stereoselective formation of chiral allylic silanes

Laura E. Bourque, Pamela A. Cleary, Keith Woerpel

Research output: Contribution to journalArticle

Abstract

Silylene insertion into allylic ethers occurs suprafacially to provide enantioenriched allylic silanes and disilanes. Silylene insertion to a variety of protected allylic alcohols utilizing silver- and copper-mediated conditions proved to be a general method for allylic silane formation. Allylic disilanes reacted similarly to allylic silanes, undergoing both annulation and allylation reactions.

Original languageEnglish (US)
Pages (from-to)12602-12603
Number of pages2
JournalJournal of the American Chemical Society
Volume129
Issue number42
DOIs
StatePublished - Oct 24 2007

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Silanes
Ethers
Metals
Allylation
Silver
Copper
Alcohols

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Metal-catalyzed silylene insertions of allylic ethers : Stereoselective formation of chiral allylic silanes. / Bourque, Laura E.; Cleary, Pamela A.; Woerpel, Keith.

In: Journal of the American Chemical Society, Vol. 129, No. 42, 24.10.2007, p. 12602-12603.

Research output: Contribution to journalArticle

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