Mechanics and electrochemistry of ionic polymer metal composites

Youngsu Cha, Maurizio Porfiri

Research output: Contribution to journalArticle

Abstract

Ionic polymer metal composites (IPMCs) are electroactive materials composed of a hydrated ionomeric membrane that is sandwiched between noble metal electrodes. Here, we propose a modeling framework to study quasi-static large deformations and electrochemistry of IPMCs. Specifically, IPMC kinematics is described in terms of its mechanical deformation, the concentration of mobile counterions neutralizing the ionomer, and the electric potential. The chemoelectromechanical constitutive behavior is obtained from a Helmholtz free energy density, which accounts for mechanical stretching, ion mixing, and electric polarization. The three-dimensional framework is specialized to plane bending of thin IPMCs. Hence, we propose a structural model, where the moment and the charge stored along the IPMC are computed from the solution of a modified Poisson-Nernst-Planck system, in terms of the through-the-thickness coordinate. For small static deformations, we present a semianalytical solution based on the method of matched asymptotic expansions, which is ultimately used to study IPMC sensing and actuation. We demonstrate that the linearity of IPMC actuation in a broad voltage range could be attributed to the interplay of two competing nonlinear phenomena, associated with Maxwell stress and osmotic pressure. In agreement with experimental observations, our model confirms the possibility of tailoring IPMC actuation by varying the counterion size and the concentration of fixed ions. Finally, the model is successful in predicting the significantly different voltage levels displayed by IPMC sensors and actuators, which are associated with remarkable variations in the ion mixing and polarization energies.

Original languageEnglish (US)
Pages (from-to)156-178
Number of pages23
JournalJournal of the Mechanics and Physics of Solids
Volume71
Issue number1
DOIs
StatePublished - 2014

Fingerprint

Electrochemistry
electrochemistry
Mechanics
composite materials
Composite materials
polymers
Polymers
Metals
metals
actuation
Ions
Electric potential
electric potential
Polarization
static deformation
ions
osmosis
Ionomers
polarization
Precious metals

Keywords

  • Asymptotic analysis
  • Electromigration
  • Ionic polymer metal composite
  • Ions
  • Sensors and actuators

ASJC Scopus subject areas

  • Mechanical Engineering
  • Mechanics of Materials
  • Condensed Matter Physics

Cite this

Mechanics and electrochemistry of ionic polymer metal composites. / Cha, Youngsu; Porfiri, Maurizio.

In: Journal of the Mechanics and Physics of Solids, Vol. 71, No. 1, 2014, p. 156-178.

Research output: Contribution to journalArticle

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