Mechanical bond formation by radical templation

Hao Li, Albert C. Fahrenbach, Sanjeev K. Dey, Subhadeep Basu, Ali Trabolsi, Zhixue Zhu, Youssry Y. Botros, J. Fraser Stoddart

Research output: Contribution to journalArticle

Abstract

A radical interaction has been employed as the recognition motif in the template-directed synthesis of a [2]rotaxane composed of cyclobis(paraquat-p- phenylene) and a viologen derivative. The ruthenium tris(bipyridine)/ triethanolamine system is used as the electron-transfer photocatalyst to generate the necessary radical cation components that result in the formation of an inclusion complex. A stoppering reaction follows to form the mechanical bond.

Original languageEnglish (US)
Pages (from-to)8260-8265
Number of pages6
JournalAngewandte Chemie - International Edition
Volume49
Issue number44
DOIs
StatePublished - Oct 25 2010

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Keywords

  • Electrochemistry
  • Radical dimerization
  • Rotaxanes
  • Self-assembly
  • Template-directed synthesis

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

Li, H., Fahrenbach, A. C., Dey, S. K., Basu, S., Trabolsi, A., Zhu, Z., Botros, Y. Y., & Stoddart, J. F. (2010). Mechanical bond formation by radical templation. Angewandte Chemie - International Edition, 49(44), 8260-8265. https://doi.org/10.1002/anie.201004488