Light-activated self-propelled colloids

J. Palacci, S. Sacanna, S. H. Kim, G. R. Yi, D. J. Pine, P. M. Chaikin

Research output: Contribution to journalArticle

Abstract

Light-activated self-propelled colloids are synthesized and their active motion is studied using optical microscopy. We propose a versatile route using different photoactive materials, and demonstrate a multiwavelength activation and propulsion. Thanks to the photoelectrochemical properties of two semiconductor materials (α-Fe2O3 and TiO2), a light with an energy higher than the bandgap triggers the reaction of decomposition of hydrogen peroxide and produces a chemical cloud around the particle. It induces a phoretic attraction with neighbouring colloids as well as an osmotic selfpropulsion of the particle on the substrate. We use these mechanisms to form colloidal cargos as well as self-propelled particles where the light-activated component is embedded into a dielectric sphere. The particles are self-propelled along a direction otherwise randomized by thermal fluctuations, and exhibit a persistent random walk. For sufficient surface density, the particles spontaneously form 'living crystals' which are mobile, break apart and reform. Steering the particle with an external magnetic field, we show that the formation of the dense phase results fromthe collisions heads-on of the particles. This effect is intrinsically non-equilibrium and a novel principle of organization for systems without detailed balance. Engineering families of particles self-propelled by different wavelength demonstrate a good understanding of both the physics and the chemistry behind the system and points to a general route for designing new families of self-propelled particles.

Original languageEnglish (US)
Article number20130372
JournalPhilosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences
Volume372
Issue number2029
DOIs
StatePublished - Nov 28 2014

Fingerprint

Colloids
colloids
Hydrogen peroxide
Propulsion
Particles (particulate matter)
Optical microscopy
Energy gap
Physics
Chemical activation
Semiconductor materials
Magnetic fields
Decomposition
Wavelength
Crystals
chemical clouds
Substrates
routes
Hydrogen Peroxide
Detailed Balance
TiO2

Keywords

  • Active colloids
  • Colloidal synthesis
  • Self-organization

ASJC Scopus subject areas

  • Mathematics(all)
  • Physics and Astronomy(all)
  • Engineering(all)

Cite this

Light-activated self-propelled colloids. / Palacci, J.; Sacanna, S.; Kim, S. H.; Yi, G. R.; Pine, D. J.; Chaikin, P. M.

In: Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 372, No. 2029, 20130372, 28.11.2014.

Research output: Contribution to journalArticle

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