Kinematic and mechanical profile of the self-actuation of thermosalient crystal twins of 1,2,4,5-tetrabromobenzene: A molecular crystalline analogue of a bimetallic strip

Subash Chandra Sahoo, Shashi Bhushan Sinha, M. S.R.N. Kiran, Upadrasta Ramamurty, Arcan F. Dericioglu, C. Malla Reddy, Pance Naumov

Research output: Contribution to journalArticle

Abstract

A paradigm shift from hard to flexible, organic-based optoelectronics requires fast and reversible mechanical response from actuating materials that are used for conversion of heat or light into mechanical motion. As the limits in the response times of polymer-based actuating materials are reached, which are inherent to the less-than-optimal coupling between the light/heat and mechanical energy in them, a conceptually new approach to mechanical actuation is required to leapfrog the performance of organic actuators. Herein, we explore single crystals of 1,2,4,5-tetrabromobenzene (TBB) as actuating elements and establish relations between their kinematic profile and mechanical properties. Centimeter-size acicular crystals of TBB are the only naturally twinned crystals out of about a dozen known materials that exhibit the thermosalient effect - an extremely rare and visually impressive crystal locomotion. When taken over a phase transition, crystals of this material store mechanical strain and are rapidly self-actuated to sudden jumps to release the internal strain, leaping up to several centimeters. To establish the structural basis for this colossal crystal motility, we investigated the mechanical profile of the crystals from macroscale, in response to externally induced deformation under microscope, to nanoscale, by using nanoindentation. Kinematic analysis based on high-speed recordings of over 200 twinned TBB crystals exposed to directional or nondirectional heating unraveled that the crystal locomotion is a kinematically complex phenomenon that includes at least six kinematic effects. The nanoscale tests confirm the highly elastic nature, with an elastic deformation recovery (60%) that is far superior to those of molecular crystals reported earlier. This property appears to be critical for accumulation of stress required for crystal jumping. Twinned crystals of TBB exposed to moderate directional heating behave as all-organic analogue of a bimetallic strip, where the lattice misfit between the two crystal components drives reversible deformation of the crystal.

Original languageEnglish (US)
Pages (from-to)13843-13850
Number of pages8
JournalJournal of the American Chemical Society
Volume135
Issue number37
DOIs
StatePublished - Sep 18 2013

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Biomechanical Phenomena
Kinematics
Locomotion
Crystalline materials
Heating
Crystals
Hot Temperature
Light
Phase Transition
Reaction Time
Polymers
1,2,4,5-tetrabromobenzene
Molecular crystals
Elastic deformation
Nanoindentation
Crystal lattices
Optoelectronic devices
Microscopes
Actuators
Phase transitions

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Kinematic and mechanical profile of the self-actuation of thermosalient crystal twins of 1,2,4,5-tetrabromobenzene : A molecular crystalline analogue of a bimetallic strip. / Sahoo, Subash Chandra; Sinha, Shashi Bhushan; Kiran, M. S.R.N.; Ramamurty, Upadrasta; Dericioglu, Arcan F.; Reddy, C. Malla; Naumov, Pance.

In: Journal of the American Chemical Society, Vol. 135, No. 37, 18.09.2013, p. 13843-13850.

Research output: Contribution to journalArticle

Sahoo, Subash Chandra ; Sinha, Shashi Bhushan ; Kiran, M. S.R.N. ; Ramamurty, Upadrasta ; Dericioglu, Arcan F. ; Reddy, C. Malla ; Naumov, Pance. / Kinematic and mechanical profile of the self-actuation of thermosalient crystal twins of 1,2,4,5-tetrabromobenzene : A molecular crystalline analogue of a bimetallic strip. In: Journal of the American Chemical Society. 2013 ; Vol. 135, No. 37. pp. 13843-13850.
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abstract = "A paradigm shift from hard to flexible, organic-based optoelectronics requires fast and reversible mechanical response from actuating materials that are used for conversion of heat or light into mechanical motion. As the limits in the response times of polymer-based actuating materials are reached, which are inherent to the less-than-optimal coupling between the light/heat and mechanical energy in them, a conceptually new approach to mechanical actuation is required to leapfrog the performance of organic actuators. Herein, we explore single crystals of 1,2,4,5-tetrabromobenzene (TBB) as actuating elements and establish relations between their kinematic profile and mechanical properties. Centimeter-size acicular crystals of TBB are the only naturally twinned crystals out of about a dozen known materials that exhibit the thermosalient effect - an extremely rare and visually impressive crystal locomotion. When taken over a phase transition, crystals of this material store mechanical strain and are rapidly self-actuated to sudden jumps to release the internal strain, leaping up to several centimeters. To establish the structural basis for this colossal crystal motility, we investigated the mechanical profile of the crystals from macroscale, in response to externally induced deformation under microscope, to nanoscale, by using nanoindentation. Kinematic analysis based on high-speed recordings of over 200 twinned TBB crystals exposed to directional or nondirectional heating unraveled that the crystal locomotion is a kinematically complex phenomenon that includes at least six kinematic effects. The nanoscale tests confirm the highly elastic nature, with an elastic deformation recovery (60{\%}) that is far superior to those of molecular crystals reported earlier. This property appears to be critical for accumulation of stress required for crystal jumping. Twinned crystals of TBB exposed to moderate directional heating behave as all-organic analogue of a bimetallic strip, where the lattice misfit between the two crystal components drives reversible deformation of the crystal.",
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