Isostructural Cocrystals of 1,3,5-Trinitrobenzene Assembled by Halogen Bonding

Jonathan C. Bennion, Leslie Vogt, Mark Tuckerman, Adam J. Matzger

Research output: Contribution to journalArticle

Abstract

Two isostructural energetic cocrystals containing 1,3,5-trinitrobenzene (TNB) were obtained with the energetic materials 1,3,5-triiodo-2,4,6-trinitrobenzene (TITNB) and 1,3,5-tribromo-2,4,6-trinitrobenzene (TBTNB) in ratios of 2:1 TNB/TITNB (1) and 2:1 TNB/TBTNB (2). These materials contain the shortest nitro-iodo and second shortest nitro-bromo interactions seen in the Cambridge Structural Database for organohalides. Computational studies indicate that the cocrystals are more stable than their respective component crystals by 11.5 kJ/mol for 1 and 8.2 kJ/mol for 2. While the formation of an isostructural 2:1 cocrystal with 1,3,5-trichloro-2,4,6-trinitrobenzene (TCTNB) was calculated to be favorable by 8.5 kJ/mol, only a physical mixture of the two coformers was obtained experimentally. Both 1 and 2 possess high crystallographic densities (2.203 and 1.980 g/cm3, respectively) and were found to be insensitive in small-scale impact drop tests, possessing sensitivity between that of TNB and TXTNB (X = I or Br). The halogen content of the two cocrystals suggests application as insensitive biocidal energetics. Halogen bonding, facilitated by the strong polarization induced by aromatic ring nitration, plays a critical role in the formation of these cocrystals and offers a promising route to the development of new energetic cocrystals.

Original languageEnglish (US)
Pages (from-to)4688-4693
Number of pages6
JournalCrystal Growth and Design
Volume16
Issue number8
DOIs
StatePublished - Aug 3 2016

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Nitration
Halogens
halogens
drop tests
Trinitrobenzenes
Polarization
nitration
Crystals
routes
sensitivity
rings
polarization
crystals
interactions
sym-trinitrobenzene

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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Isostructural Cocrystals of 1,3,5-Trinitrobenzene Assembled by Halogen Bonding. / Bennion, Jonathan C.; Vogt, Leslie; Tuckerman, Mark; Matzger, Adam J.

In: Crystal Growth and Design, Vol. 16, No. 8, 03.08.2016, p. 4688-4693.

Research output: Contribution to journalArticle

Bennion, Jonathan C. ; Vogt, Leslie ; Tuckerman, Mark ; Matzger, Adam J. / Isostructural Cocrystals of 1,3,5-Trinitrobenzene Assembled by Halogen Bonding. In: Crystal Growth and Design. 2016 ; Vol. 16, No. 8. pp. 4688-4693.
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