### Abstract

Irreducible spherical tensor analysis can be used to select both the order and the rank of tensor componenets of the density matrix. This procedure was demonstrated for a collection of dipolar-coupled spin I = frac(1, 2) nuclei. In this work we adapt this approach for quadrupolar nuclei. We demonstrate this technique using the I = frac(7, 2) NMR spectra from ^{133}Cs in an anisotropic phase. The separation of all possible ranks is shown. In this form the experiment can be useful in the analysis of both coherent and dissipative dynamics of quadrupolar nuclei.

Original language | English (US) |
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Pages (from-to) | 235-239 |

Number of pages | 5 |

Journal | Chemical Physics Letters |

Volume | 464 |

Issue number | 4-6 |

DOIs | |

State | Published - Oct 23 2008 |

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### ASJC Scopus subject areas

- Physical and Theoretical Chemistry
- Physics and Astronomy(all)

### Cite this

*Chemical Physics Letters*,

*464*(4-6), 235-239. https://doi.org/10.1016/j.cplett.2008.08.072

**Irreducible spherical tensor analysis of quadrupolar nuclei.** / Chandra Shekar, S.; Rong, Peng; Jerschow, Alexej.

Research output: Contribution to journal › Article

*Chemical Physics Letters*, vol. 464, no. 4-6, pp. 235-239. https://doi.org/10.1016/j.cplett.2008.08.072

}

TY - JOUR

T1 - Irreducible spherical tensor analysis of quadrupolar nuclei

AU - Chandra Shekar, S.

AU - Rong, Peng

AU - Jerschow, Alexej

PY - 2008/10/23

Y1 - 2008/10/23

N2 - Irreducible spherical tensor analysis can be used to select both the order and the rank of tensor componenets of the density matrix. This procedure was demonstrated for a collection of dipolar-coupled spin I = frac(1, 2) nuclei. In this work we adapt this approach for quadrupolar nuclei. We demonstrate this technique using the I = frac(7, 2) NMR spectra from 133Cs in an anisotropic phase. The separation of all possible ranks is shown. In this form the experiment can be useful in the analysis of both coherent and dissipative dynamics of quadrupolar nuclei.

AB - Irreducible spherical tensor analysis can be used to select both the order and the rank of tensor componenets of the density matrix. This procedure was demonstrated for a collection of dipolar-coupled spin I = frac(1, 2) nuclei. In this work we adapt this approach for quadrupolar nuclei. We demonstrate this technique using the I = frac(7, 2) NMR spectra from 133Cs in an anisotropic phase. The separation of all possible ranks is shown. In this form the experiment can be useful in the analysis of both coherent and dissipative dynamics of quadrupolar nuclei.

UR - http://www.scopus.com/inward/record.url?scp=53549102197&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=53549102197&partnerID=8YFLogxK

U2 - 10.1016/j.cplett.2008.08.072

DO - 10.1016/j.cplett.2008.08.072

M3 - Article

VL - 464

SP - 235

EP - 239

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 4-6

ER -