Iron(III) nitrilotriacetate and iron(III) iminodiacetate, their X-ray crystallographic structures and chemical properties

Marc Walters, Vadim Vapnyar, Adam Bolour, Chris Incarvito, Arnold L. Rheingold

Research output: Contribution to journalArticle

Abstract

Mononuclear iron(III) nitrilotriacetato dichloride, [Fe(nta)Cl 2] 2-, and iron(III) bis-iminodiacetato, [Fe(ida) 2] -, complexes were formed in py, from which they were isolated and characterized by X-ray crystallography. The iron-nta complex is the structurally simplest of the reported solid state iron-nta complexes, and is catalytic for the air oxidation of hydrogen sulfide to sulfur.

Original languageEnglish (US)
Pages (from-to)941-946
Number of pages6
JournalPolyhedron
Volume22
Issue number7
StatePublished - Apr 1 2003

Fingerprint

chemical properties
Chemical properties
Iron
X-Rays
iron
X rays
x rays
Hydrogen Sulfide
hydrogen sulfide
dichlorides
X ray crystallography
X Ray Crystallography
Hydrogen sulfide
Sulfur
crystallography
sulfur
Air
solid state
Oxidation
oxidation

Keywords

  • Crystal structures
  • Hydrogen sulfide
  • Iminodiacetate
  • Iron
  • Nitrilotriacetate

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Iron(III) nitrilotriacetate and iron(III) iminodiacetate, their X-ray crystallographic structures and chemical properties. / Walters, Marc; Vapnyar, Vadim; Bolour, Adam; Incarvito, Chris; Rheingold, Arnold L.

In: Polyhedron, Vol. 22, No. 7, 01.04.2003, p. 941-946.

Research output: Contribution to journalArticle

Walters, M, Vapnyar, V, Bolour, A, Incarvito, C & Rheingold, AL 2003, 'Iron(III) nitrilotriacetate and iron(III) iminodiacetate, their X-ray crystallographic structures and chemical properties', Polyhedron, vol. 22, no. 7, pp. 941-946.
Walters, Marc ; Vapnyar, Vadim ; Bolour, Adam ; Incarvito, Chris ; Rheingold, Arnold L. / Iron(III) nitrilotriacetate and iron(III) iminodiacetate, their X-ray crystallographic structures and chemical properties. In: Polyhedron. 2003 ; Vol. 22, No. 7. pp. 941-946.
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AU - Rheingold, Arnold L.

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