Ion partitioning at the oil-water interface as a source of tunable electrostatic effects in emulsions with colloids

Mirjam E. Leunissen, Jos Zwanikken, René Van Roij, Paul M. Chaikin, Alfons Van Blaaderen

    Research output: Contribution to journalArticle

    Abstract

    We present a combined experimental and theoretical investigation of the surprisingly strong electrostatic effects that can occur in mixtures of low- and high-polar liquids (e.g. oil-water emulsions), here in the presence of colloidal particles. For our experiments, we used confocal microscopy imaging, supplemented with electrophoresis and conductivity measurements. Theoretically, we studied our systems by means of a modified Poisson-Boltzmann theory, which takes into account image charge effects and the electrostatic self-energies of the micro-ions in the different dielectric media. Our results show that the unequal partitioning of micro-ions between the two liquid phases is the common driving force behind most of the observed electrostatic effects. The structural signatures of these effects typically develop on a time scale of hours to days and are qualitatively well-described by our theory. We demonstrate how the partitioning process and its associated phenomena can be controlled by shifting the balance of the interlocked ionic dissociation and partitioning equilibria. Moreover, we present strong experimental proof that the two-dimensional colloidal crystals at the oil-water interface are due to long-ranged Coulombic repulsion through the oil phase. The acquired insight in the role of electrostatics in oil-water emulsions is important for understanding the interactions in particle-stabilized ('Pickering') and charge-stabilized emulsions, emulsion production, encapsulation and self-assembly.

    Original languageEnglish (US)
    Pages (from-to)6405-6414
    Number of pages10
    JournalPhysical Chemistry Chemical Physics
    Volume9
    Issue number48
    DOIs
    StatePublished - 2007

    Fingerprint

    Colloids
    Emulsions
    emulsions
    colloids
    Electrostatics
    Oils
    oils
    Ions
    electrostatics
    Water
    water
    ions
    Confocal microscopy
    Liquids
    electrophoresis
    Electrophoresis
    Encapsulation
    Self assembly
    self assembly
    liquid phases

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Atomic and Molecular Physics, and Optics

    Cite this

    Ion partitioning at the oil-water interface as a source of tunable electrostatic effects in emulsions with colloids. / Leunissen, Mirjam E.; Zwanikken, Jos; Van Roij, René; Chaikin, Paul M.; Van Blaaderen, Alfons.

    In: Physical Chemistry Chemical Physics, Vol. 9, No. 48, 2007, p. 6405-6414.

    Research output: Contribution to journalArticle

    Leunissen, Mirjam E. ; Zwanikken, Jos ; Van Roij, René ; Chaikin, Paul M. ; Van Blaaderen, Alfons. / Ion partitioning at the oil-water interface as a source of tunable electrostatic effects in emulsions with colloids. In: Physical Chemistry Chemical Physics. 2007 ; Vol. 9, No. 48. pp. 6405-6414.
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