Intermolecular silacarbonyl ylide cycloadditions: A direct pathway to oxasilacyclopentenes

Laura E. Bourque, Keith Woerpel

Research output: Contribution to journalArticle

Abstract

(Chemical Equation Presented) Silacarbonyl ylides, generated by metal-catalyzed silylene transfer to carbonyls, participate in formal intermolecular 1,3-dipolar cycloaddition reactions with carbonyl compounds and alkynes to form dioxasilacyclopentane acetals and oxasilacyclopentenes in an efficient, one-step process.

Original languageEnglish (US)
Pages (from-to)5257-5260
Number of pages4
JournalOrganic Letters
Volume10
Issue number22
DOIs
StatePublished - 2008

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acetals
Carbonyl compounds
Acetals
carbonyl compounds
Alkynes
Cycloaddition
Cycloaddition Reaction
cycloaddition
alkynes
Metals
metals

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry

Cite this

Intermolecular silacarbonyl ylide cycloadditions : A direct pathway to oxasilacyclopentenes. / Bourque, Laura E.; Woerpel, Keith.

In: Organic Letters, Vol. 10, No. 22, 2008, p. 5257-5260.

Research output: Contribution to journalArticle

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